Polyurethane as Novel Catalyst for the Propoxylation of Fatty Amines

Pia Müller, Maria Fernanda Neira d'Angelo, John van der Schaaf (Corresponding author)

Research output: Contribution to journalArticleAcademicpeer-review

Abstract

The propoxylation of fatty amines is a crucial reaction in the industrial production of surfactants. Catalyzing this reaction has so far proven unrewarding due to severe selectivity losses. In this study, rigid foam-structured polyurethane, i. e., an extremely inexpensive material which has not been used as a catalyst ever before, shows an unprecedented catalytic activity during the in-flow propoxylation of octylamine. The foam cells contain bound hydroxyl and amine groups that result in a bifunctional catalyst able to destabilize the ring structure of propylene oxide, and thus catalyze further propoxylation of fatty amines. An outstanding 10-fold reduction of the residence time without any loss of selectivity is achieved with respect to the un-catalyzed process. Furthermore, the polyurethane foam showed stable time-on-stream performance up to 10 bar and 110 °C.

Original languageEnglish
Pages (from-to)2947-2950
Number of pages4
JournalChemCatChem
Volume12
Issue number11
DOIs
Publication statusPublished - 5 Jun 2020

Keywords

  • amines
  • autocatalysis
  • epoxidation
  • heterogeneous catalysis
  • polyurethane foam

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