Polymerisation in supported bilayers

M. Jung; A.L. German; H.R. Fischer

doi:10.1007/s003960000378

Polymerisation in supported bilayers

M. Jung, A.L. German, H.R. Fischer

Chemical Engineering and Chemistry

Research output: Contribution to journal › Article › Academic › peer-review

8 Citations (Scopus)

Abstract

The intercalation of the twin-tailed amphiphilic dioctadecyldimethylammonium (DODA) ions in smectite clay minerals provides a well-defined supported bilayer system. Polymerisation of styrene in these robust model bilayers allows one to focus on the effect of the constrained medium on the polymerisation process and the polymer. Small-angle X-ray scattering analysis and differential scanning calorimetry data indicated that the polymerisation of styrene in DODA–montmorillonite leads to phase separation between polystyrene and the surfactant matrix.

Original language	English
Pages (from-to)	1114-1118
Number of pages	4
Journal	Colloid and Polymer Science
Volume	278
Issue number	11
DOIs	https://doi.org/10.1007/s003960000378
Publication status	Published - 2000

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10.1007/s003960000378

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title = "Polymerisation in supported bilayers",

abstract = "The intercalation of the twin-tailed amphiphilic dioctadecyldimethylammonium (DODA) ions in smectite clay minerals provides a well-defined supported bilayer system. Polymerisation of styrene in these robust model bilayers allows one to focus on the effect of the constrained medium on the polymerisation process and the polymer. Small-angle X-ray scattering analysis and differential scanning calorimetry data indicated that the polymerisation of styrene in DODA–montmorillonite leads to phase separation between polystyrene and the surfactant matrix.",

author = "M. Jung and A.L. German and H.R. Fischer",

year = "2000",

doi = "10.1007/s003960000378",

language = "English",

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journal = "Colloid and Polymer Science",

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T1 - Polymerisation in supported bilayers

AU - Jung, M.

AU - German, A.L.

AU - Fischer, H.R.

PY - 2000

Y1 - 2000

N2 - The intercalation of the twin-tailed amphiphilic dioctadecyldimethylammonium (DODA) ions in smectite clay minerals provides a well-defined supported bilayer system. Polymerisation of styrene in these robust model bilayers allows one to focus on the effect of the constrained medium on the polymerisation process and the polymer. Small-angle X-ray scattering analysis and differential scanning calorimetry data indicated that the polymerisation of styrene in DODA–montmorillonite leads to phase separation between polystyrene and the surfactant matrix.

AB - The intercalation of the twin-tailed amphiphilic dioctadecyldimethylammonium (DODA) ions in smectite clay minerals provides a well-defined supported bilayer system. Polymerisation of styrene in these robust model bilayers allows one to focus on the effect of the constrained medium on the polymerisation process and the polymer. Small-angle X-ray scattering analysis and differential scanning calorimetry data indicated that the polymerisation of styrene in DODA–montmorillonite leads to phase separation between polystyrene and the surfactant matrix.

U2 - 10.1007/s003960000378

DO - 10.1007/s003960000378

M3 - Article

SN - 0303-402X

VL - 278

SP - 1114

EP - 1118

JO - Colloid and Polymer Science

JF - Colloid and Polymer Science

IS - 11

ER -

Polymerisation in supported bilayers

Abstract

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