Abstract
Metallo-supramolecular initiators based on 6-mono and 6,6'-bis-functionalized 2,2'-bipyridine metal complexes were utilized for the polymerization of different 2-oxazoline monomers. Polymers with a narrow molecular weight distribution and a predetermined molecular weight were obtained. The homo and block copolymers were characterized by GPC. Shear forces (e.g. on the GPC column) had a distinct influence on the star-like architecture, resulting in partially destruction.
Original language | English |
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Pages (from-to) | 245-253 |
Number of pages | 9 |
Journal | Designed Monomers and Polymers |
Volume | 3 |
Issue number | 3 |
DOIs | |
Publication status | Published - 2000 |
Externally published | Yes |