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Platinum-promoted Ga/Al2O3 as highly active, selective, and stable catalyst for the dehydrogenation of Propane

  • J.J.H.B. Sattler
  • , I.D. Gonzalez-Jimenez
  • , L. Luo
  • , B.A. Stears
  • , A. Malek
  • , D.G. Barton
  • , B.A. Kilos
  • , M.P. Kaminsky
  • , M.W.G.M. Verhoeven
  • , E.J. Koers
  • , M. Baldus
  • , B.M. Weckhuysen

    Research output: Contribution to journalArticleAcademicpeer-review

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    Abstract

    A novel catalyst material for the selective dehydrogenation of propane is presented. The catalyst consists of 1000 ppm Pt, 3 wt¿% Ga, and 0.25 wt¿% K supported on alumina. We observed a synergy between Ga and Pt, resulting in a highly active and stable catalyst. Additionally, we propose a bifunctional active phase, in which coordinately unsaturated Ga3+ species are the active species and where Pt functions as a promoter.
    Original languageEnglish
    Pages (from-to)9251-9256
    Number of pages6
    JournalAngewandte Chemie - International Edition
    Volume53
    Issue number35
    DOIs
    Publication statusPublished - 2014

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