Plasma-assisted and thermal atomic layer deposition of electrochemically active Li2CO3

N. Hornsveld, B.H.F. Put, W.M.M. Kessels, P.M. Vereecken, M. Creatore

Research output: Contribution to journalArticleAcademicpeer-review

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Abstract

Thin-film lithium carbonate (Li2CO3) has applications in various electrochemical devices, like Li-ion batteries, gas sensors and fuel cells. ALD of Li2CO3 is of interest for these applications as it allows for uniform and conformal coating of high-aspect ratio structures and particles with very precise thickness control. However, there are few studies that focus on its fabrication and characterization. In this work, plasma-assisted and thermal ALD were adopted to grow ultra-thin, conformal Li2CO3 films between 50 and 300 °C using lithium tert-butoxide as a precursor and O2 plasma or H2O/CO2 as co-reactants. More specifically, we focus on the plasma-assisted process by film growth, stability and conductivity studies and emphasize the differences from its more extensively adopted thermal counterpart. Plasma-assisted ALD allows for higher growth per cycle values (0.82 vs. 0.60 Å), lower substrate temperatures and shorter cycle times. The stoichiometry of the films, ranging from Li2CO3 to Li2O, can be controlled by substrate temperature and O2 plasma exposure time. The ionic conductivity for both plasma-assisted and thermal ALD is measured for the first time and is in the order of 10-10 S cm-1 after normalizing to the different effective surface areas. The Li-ion conductivities found here are in line with literature values predicted by simulation studies.

Original languageEnglish
Pages (from-to)41359-41368
Number of pages10
JournalRSC Advances
Volume7
Issue number66
DOIs
Publication statusPublished - 24 Aug 2017

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Plasma Gases
Atomic layer deposition
Plasmas
Thickness control
Lithium Carbonate
Gas fuels
Lithium
Film growth
Substrates
Ionic conductivity
Chemical sensors
Stoichiometry
Fuel cells
Aspect ratio
Ions
Fabrication
Thin films
Coatings
Temperature
Hot Temperature

Cite this

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title = "Plasma-assisted and thermal atomic layer deposition of electrochemically active Li2CO3",
abstract = "Thin-film lithium carbonate (Li2CO3) has applications in various electrochemical devices, like Li-ion batteries, gas sensors and fuel cells. ALD of Li2CO3 is of interest for these applications as it allows for uniform and conformal coating of high-aspect ratio structures and particles with very precise thickness control. However, there are few studies that focus on its fabrication and characterization. In this work, plasma-assisted and thermal ALD were adopted to grow ultra-thin, conformal Li2CO3 films between 50 and 300 °C using lithium tert-butoxide as a precursor and O2 plasma or H2O/CO2 as co-reactants. More specifically, we focus on the plasma-assisted process by film growth, stability and conductivity studies and emphasize the differences from its more extensively adopted thermal counterpart. Plasma-assisted ALD allows for higher growth per cycle values (0.82 vs. 0.60 {\AA}), lower substrate temperatures and shorter cycle times. The stoichiometry of the films, ranging from Li2CO3 to Li2O, can be controlled by substrate temperature and O2 plasma exposure time. The ionic conductivity for both plasma-assisted and thermal ALD is measured for the first time and is in the order of 10-10 S cm-1 after normalizing to the different effective surface areas. The Li-ion conductivities found here are in line with literature values predicted by simulation studies.",
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Plasma-assisted and thermal atomic layer deposition of electrochemically active Li2CO3. / Hornsveld, N.; Put, B.H.F.; Kessels, W.M.M.; Vereecken, P.M.; Creatore, M.

In: RSC Advances, Vol. 7, No. 66, 24.08.2017, p. 41359-41368.

Research output: Contribution to journalArticleAcademicpeer-review

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AU - Put, B.H.F.

AU - Kessels, W.M.M.

AU - Vereecken, P.M.

AU - Creatore, M.

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