Piston rotaxane monolayers: shear swelling and nanovalve behavior

Ruud Boesten, E.M. Sevick, D.R.M. Williams

Research output: Contribution to journalArticleAcademicpeer-review

8 Citations (Scopus)

Abstract

A piston-rotaxane is a rotaxane molecule where one of the free rings is attached to a rod-like polymer (the piston). We examine the behavior of a system of piston rotaxanes grafted by one end to a surface in the presence of a fluid flow. At a critical shear rate the rotaxane layer will extend perpendicular to the surface, i.e. the system undergoes shear-induced swelling. When the inside surface of a narrow tube is coated with these rotaxanes a nanovalve can be created which has a highly nonlinear flow-rate versus pressure curve. In particular a valve can be created which limits the maximum discharge over a wide range of pressures.
Original languageEnglish
Pages (from-to)7244-7249
JournalMacromolecules
Volume43
Issue number17
DOIs
Publication statusPublished - 2010

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