pi-Dimers of end-capped oligopyrrole cation radicals

J.A.E.H. Haare, van, L. Groenendaal, E.E. Havinga, R.A.J. Janssen, E.W. Meijer

Research output: Contribution to journalArticleAcademicpeer-review

70 Citations (Scopus)
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Abstract

In two consecutive one-electron oxidations, oligopyrroles substituted with phenyl capping groups (PhPynPh, n = 2–4) can be oxidized reversibly to give stable cation radicals and dications. Spectroelectrochemical studies give direct evidence that diamagnetic p-dimers of cation radicals are formed in solution. Such dimers may be involved as charge carriers in conducting polypyrrole.
Original languageEnglish
Pages (from-to)638-640
Number of pages3
JournalAngewandte Chemie - International Edition
Volume35
Issue number6
DOIs
Publication statusPublished - 1996

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