Photopatterned liquid crystalline polymers for microactuators

A.L. Elias, K.D. Harris, C.W.M. Bastiaansen, D.J. Broer, M.J. Brett

Research output: Contribution to journalArticleAcademicpeer-review

50 Citations (Scopus)

Abstract

We have investigated the properties of thermally-responsive, patterned liquid crystalline polymers as their dimensions are scaled to a size suitable for use in microelectromechanical systems. All samples were fabricated using surface alignment and photopatterning techniques that can be used to produce integrated devices anchored on a substrate. The thermomechanical properties of free-standing macroscopic samples with varying concentration of crosslinking molecules were investigated in order to optimize the thermal response of the material. It was found that samples containing 12% crosslinker were able to expand by up 19% when heated. The thermomechanical properties of surface-anchored films were also investigated, and it was found that by employing a polymerized cholesteric structure of the liquid crystalline units a thermal expansion of up to 11% could be achieved when the sample was heated to 200 °C. Patternability was demonstrated using a simple photopatterning process that was used to fabricate samples consisting of lines of cholesteric material on a bare substrate, or alternating regions of liquid crystalline polymer in the isotropic and cholesteric phases. Actuation of these films was also demonstrated.

Original languageEnglish
Pages (from-to)2903-2912
Number of pages10
JournalJournal of Materials Chemistry
Volume16
Issue number28
DOIs
Publication statusPublished - 14 Jul 2006

Fingerprint Dive into the research topics of 'Photopatterned liquid crystalline polymers for microactuators'. Together they form a unique fingerprint.

Cite this