Abstract
Irradiation of two racemates of 4,5-dihydro-8-hydroxygermacrene B (2, 3) results, in addition to E-Z isomerization, in the occurrence of a [1,3]-C shift. Conformational differences between the diastereoisomers are reflected in a highly stereospecific photoreaction.
Original language | English |
---|---|
Pages (from-to) | 115-118 |
Journal | Recueil des Travaux Chimiques des Pays-Bas |
Volume | 103 |
Issue number | 4 |
DOIs | |
Publication status | Published - 1984 |