Photocatalytic decarboxylation of lactic acid by Pt/TiO2

B.G. van Campenhout, E.A. Pidko, E.J.M. Hensen

Research output: Contribution to journalArticleAcademicpeer-review

19 Citations (Scopus)
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Abstract

A photocatalytic route for the conversion of lactic acid to acetaldehyde in water is demonstrated. Direct UV photolysis of lactic acid yields CO2 and ethanol via a radical mechanism. Pt/TiO2 considerably increases the rate of lactic acid decarboxylation with acetaldehyde, H2 and CO2 as the main products. A concerted photodecarboxylation/dehydrogenation mechanism is proposed.
Original languageEnglish
Pages (from-to)11634-11637
JournalChemical Communications
Volume52
Issue number78
DOIs
Publication statusPublished - 16 Aug 2016

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