Phosphotungstic acid encapsulated in metal-organic framework as catalysts for carbohydrate dehydration to 5-hydroxymetrthylfurfural

Y. Zhang; V. Degirmenci; Can Li; E.J.M. Hensen

doi:10.1002/cssc.201000284

Phosphotungstic acid encapsulated in metal-organic framework as catalysts for carbohydrate dehydration to 5-hydroxymetrthylfurfural

Y. Zhang, V. Degirmenci, Can Li, E.J.M. Hensen

Inorganic Materials & Catalysis

Research output: Contribution to journal › Article › Academic › peer-review

217 Citations (Scopus)

Abstract

MIL-101, a chromium-based metal–organic framework, is known for its very large pore size, large surface area and good stability. However, applications of this material in catalysis are still limited. 5-Hydroxymethylfurfural (HMF) has been considered a renewable chemical platform for the production of liquid fuels and fine chemicals. Phosphotungstic acid, H3PW12O40 (PTA), encapsulated in MIL-101 is evaluated as a potential catalyst for the selective dehydration of fructose and glucose to 5-hydroxymethylfurfural. The results demonstrate that PTA/MIL-101 is effective for HMF production from fructose in DMSO and can be reused. This is the first example of the application of a metal–organic framework in carbohydrate dehydration.

Original language	English
Pages (from-to)	59-64
Number of pages	6
Journal	ChemSusChem
Volume	4
Issue number	1
DOIs	https://doi.org/10.1002/cssc.201000284
Publication status	Published - 2011

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1002/cssc.201000284

Cite this

@article{51744a5fa9f241dbabe6702eca1b0f75,

title = "Phosphotungstic acid encapsulated in metal-organic framework as catalysts for carbohydrate dehydration to 5-hydroxymetrthylfurfural",

abstract = "MIL-101, a chromium-based metal–organic framework, is known for its very large pore size, large surface area and good stability. However, applications of this material in catalysis are still limited. 5-Hydroxymethylfurfural (HMF) has been considered a renewable chemical platform for the production of liquid fuels and fine chemicals. Phosphotungstic acid, H3PW12O40 (PTA), encapsulated in MIL-101 is evaluated as a potential catalyst for the selective dehydration of fructose and glucose to 5-hydroxymethylfurfural. The results demonstrate that PTA/MIL-101 is effective for HMF production from fructose in DMSO and can be reused. This is the first example of the application of a metal–organic framework in carbohydrate dehydration.",

author = "Y. Zhang and V. Degirmenci and Can Li and E.J.M. Hensen",

year = "2011",

doi = "10.1002/cssc.201000284",

language = "English",

volume = "4",

pages = "59--64",

journal = "ChemSusChem",

issn = "1864-5631",

publisher = "Wiley-VCH Verlag",

number = "1",

}

TY - JOUR

T1 - Phosphotungstic acid encapsulated in metal-organic framework as catalysts for carbohydrate dehydration to 5-hydroxymetrthylfurfural

AU - Zhang, Y.

AU - Degirmenci, V.

AU - Li, Can

AU - Hensen, E.J.M.

PY - 2011

Y1 - 2011

N2 - MIL-101, a chromium-based metal–organic framework, is known for its very large pore size, large surface area and good stability. However, applications of this material in catalysis are still limited. 5-Hydroxymethylfurfural (HMF) has been considered a renewable chemical platform for the production of liquid fuels and fine chemicals. Phosphotungstic acid, H3PW12O40 (PTA), encapsulated in MIL-101 is evaluated as a potential catalyst for the selective dehydration of fructose and glucose to 5-hydroxymethylfurfural. The results demonstrate that PTA/MIL-101 is effective for HMF production from fructose in DMSO and can be reused. This is the first example of the application of a metal–organic framework in carbohydrate dehydration.

AB - MIL-101, a chromium-based metal–organic framework, is known for its very large pore size, large surface area and good stability. However, applications of this material in catalysis are still limited. 5-Hydroxymethylfurfural (HMF) has been considered a renewable chemical platform for the production of liquid fuels and fine chemicals. Phosphotungstic acid, H3PW12O40 (PTA), encapsulated in MIL-101 is evaluated as a potential catalyst for the selective dehydration of fructose and glucose to 5-hydroxymethylfurfural. The results demonstrate that PTA/MIL-101 is effective for HMF production from fructose in DMSO and can be reused. This is the first example of the application of a metal–organic framework in carbohydrate dehydration.

U2 - 10.1002/cssc.201000284

DO - 10.1002/cssc.201000284

M3 - Article

C2 - 21226212

SN - 1864-5631

VL - 4

SP - 59

EP - 64

JO - ChemSusChem

JF - ChemSusChem

IS - 1

ER -

Phosphotungstic acid encapsulated in metal-organic framework as catalysts for carbohydrate dehydration to 5-hydroxymetrthylfurfural

Abstract

UN SDGs

Access to Document

Fingerprint

Cite this