Phosphorus containing silsesquioxanes - new opportunities for homogeneous catalysis

J.I. Vlugt, van der; J. Ackerstaff; M.M.P. Grutters; R.W.J.M. Hanssen; T.W. Dijkstra; H.C.L. Abbenhuis; D. Vogt

Phosphorus containing silsesquioxanes - new opportunities for homogeneous catalysis

J.I. Vlugt, van der
, J. Ackerstaff
, M.M.P. Grutters
, R.W.J.M. Hanssen
, T.W. Dijkstra
, H.C.L. Abbenhuis
, D. Vogt

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › Academic › peer-review

Abstract

Silsesquioxanes have attracted considerable interest as sol. mol. models for silica supported catalysts. They have also been used as nano-scaled scaffolds for immobilized homogeneous catalysts. Research on homogeneous catalysis is largely dominated by phosphorus ligands, with extensive attention for new, easily accessible and modular backbones as well as tailor-made properties for specific transformations. We have set out to combine these two fields and explore the possibilities and synthetic strategies to synthesize sterically constrained, silsesquioxane based, mono- and bidentate phosphites and phosphinites. In order to understand the influence of the silsesquioxane framework on the coordination behavior of these novel P-contg. ligands, we studied their complexation with various transition metals, such as palladium, platinum, molybdenum and rhodium. The resulting complexes were characterized by NMR spectroscopy and by X-ray crystallog. Detailed results will be presented on the various aspects of these novel and attractive ligands, including preliminary catalytic results. [on SciFinder (R)]

Original language	English
Title of host publication	Abstracts of Papers, 226th ACS National Meeting, New York, NY, United States, September 7-11, 2003 (2003)
Place of Publication	New York, NY, United States,
Publisher	American Chemical Society
Pages	INOR-592
Publication status	Published - 2003
Event	226th ACS National Meeting - New York, United States Duration: 7 Sept 2003 → 11 Sept 2003

Conference

Conference	226th ACS National Meeting
Country/Territory	United States
City	New York
Period	7/09/03 → 11/09/03

Cite this

Vlugt, van der, J. I., Ackerstaff, J., Grutters, M. M. P., Hanssen, R. W. J. M., Dijkstra, T. W., Abbenhuis, H. C. L., & Vogt, D. (2003). Phosphorus containing silsesquioxanes - new opportunities for homogeneous catalysis. In Abstracts of Papers, 226th ACS National Meeting, New York, NY, United States, September 7-11, 2003 (2003) (pp. INOR-592). American Chemical Society.

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title = "Phosphorus containing silsesquioxanes - new opportunities for homogeneous catalysis",

abstract = "Silsesquioxanes have attracted considerable interest as sol. mol. models for silica supported catalysts. They have also been used as nano-scaled scaffolds for immobilized homogeneous catalysts. Research on homogeneous catalysis is largely dominated by phosphorus ligands, with extensive attention for new, easily accessible and modular backbones as well as tailor-made properties for specific transformations. We have set out to combine these two fields and explore the possibilities and synthetic strategies to synthesize sterically constrained, silsesquioxane based, mono- and bidentate phosphites and phosphinites. In order to understand the influence of the silsesquioxane framework on the coordination behavior of these novel P-contg. ligands, we studied their complexation with various transition metals, such as palladium, platinum, molybdenum and rhodium. The resulting complexes were characterized by NMR spectroscopy and by X-ray crystallog. Detailed results will be presented on the various aspects of these novel and attractive ligands, including preliminary catalytic results. [on SciFinder (R)]",

author = "\{Vlugt, van der\}, J.I. and J. Ackerstaff and M.M.P. Grutters and R.W.J.M. Hanssen and T.W. Dijkstra and H.C.L. Abbenhuis and D. Vogt",

year = "2003",

language = "English",

pages = "INOR--592",

booktitle = "Abstracts of Papers, 226th ACS National Meeting, New York, NY, United States, September 7-11, 2003 (2003)",

publisher = "American Chemical Society",

address = "United States",

note = "226th ACS National Meeting ; Conference date: 07-09-2003 Through 11-09-2003",

}

Vlugt, van der, JI, Ackerstaff, J, Grutters, MMP, Hanssen, RWJM, Dijkstra, TW, Abbenhuis, HCL & Vogt, D 2003, Phosphorus containing silsesquioxanes - new opportunities for homogeneous catalysis. in Abstracts of Papers, 226th ACS National Meeting, New York, NY, United States, September 7-11, 2003 (2003). American Chemical Society, New York, NY, United States, pp. INOR-592, 226th ACS National Meeting, New York, New York, United States, 7/09/03.

Phosphorus containing silsesquioxanes - new opportunities for homogeneous catalysis. / Vlugt, van der, J.I.; Ackerstaff, J.; Grutters, M.M.P. et al.
Abstracts of Papers, 226th ACS National Meeting, New York, NY, United States, September 7-11, 2003 (2003). New York, NY, United States,: American Chemical Society, 2003. p. INOR-592.

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › Academic › peer-review

TY - GEN

T1 - Phosphorus containing silsesquioxanes - new opportunities for homogeneous catalysis

AU - Vlugt, van der, J.I.

AU - Ackerstaff, J.

AU - Grutters, M.M.P.

AU - Hanssen, R.W.J.M.

AU - Dijkstra, T.W.

AU - Abbenhuis, H.C.L.

AU - Vogt, D.

PY - 2003

Y1 - 2003

N2 - Silsesquioxanes have attracted considerable interest as sol. mol. models for silica supported catalysts. They have also been used as nano-scaled scaffolds for immobilized homogeneous catalysts. Research on homogeneous catalysis is largely dominated by phosphorus ligands, with extensive attention for new, easily accessible and modular backbones as well as tailor-made properties for specific transformations. We have set out to combine these two fields and explore the possibilities and synthetic strategies to synthesize sterically constrained, silsesquioxane based, mono- and bidentate phosphites and phosphinites. In order to understand the influence of the silsesquioxane framework on the coordination behavior of these novel P-contg. ligands, we studied their complexation with various transition metals, such as palladium, platinum, molybdenum and rhodium. The resulting complexes were characterized by NMR spectroscopy and by X-ray crystallog. Detailed results will be presented on the various aspects of these novel and attractive ligands, including preliminary catalytic results. [on SciFinder (R)]

AB - Silsesquioxanes have attracted considerable interest as sol. mol. models for silica supported catalysts. They have also been used as nano-scaled scaffolds for immobilized homogeneous catalysts. Research on homogeneous catalysis is largely dominated by phosphorus ligands, with extensive attention for new, easily accessible and modular backbones as well as tailor-made properties for specific transformations. We have set out to combine these two fields and explore the possibilities and synthetic strategies to synthesize sterically constrained, silsesquioxane based, mono- and bidentate phosphites and phosphinites. In order to understand the influence of the silsesquioxane framework on the coordination behavior of these novel P-contg. ligands, we studied their complexation with various transition metals, such as palladium, platinum, molybdenum and rhodium. The resulting complexes were characterized by NMR spectroscopy and by X-ray crystallog. Detailed results will be presented on the various aspects of these novel and attractive ligands, including preliminary catalytic results. [on SciFinder (R)]

M3 - Conference contribution

SP - INOR-592

BT - Abstracts of Papers, 226th ACS National Meeting, New York, NY, United States, September 7-11, 2003 (2003)

PB - American Chemical Society

CY - New York, NY, United States,

T2 - 226th ACS National Meeting

Y2 - 7 September 2003 through 11 September 2003

ER -

Phosphorus containing silsesquioxanes - new opportunities for homogeneous catalysis

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