Abstract
Formation of diffusion zone morphologies periodic in time and space during metal-ceramic reactions is considered as a manifestation of the Kirkendall effect. In a diffusion-controlled interaction, the Kirkendall marker plane can bifurcate, which is attributed to diverging vacancies fluxes in the reaction zone. When the Kirkendall plane is present in a phase layer, it attracts in situ-produced inclusions of "secondary-formed phase", which in turn, can result in a highly patterned microsctucture.
| Original language | English |
|---|---|
| Pages (from-to) | 136-145 |
| Journal | Advances in Science and Technology |
| Volume | 46 |
| DOIs | |
| Publication status | Published - 2006 |
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