Periodic pattern formation in metal-ceramic reactions

A. Kodentsov, F.J.J. Loo, van

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Abstract

Formation of diffusion zone morphologies periodic in time and space during metal-ceramic reactions is considered as a manifestation of the Kirkendall effect. In a diffusion-controlled interaction, the Kirkendall marker plane can bifurcate, which is attributed to diverging vacancies fluxes in the reaction zone. When the Kirkendall plane is present in a phase layer, it attracts in situ-produced inclusions of "secondary-formed phase", which in turn, can result in a highly patterned microsctucture.
Original languageEnglish
Pages (from-to)136-145
JournalAdvances in Science and Technology
Volume46
DOIs
Publication statusPublished - 2006

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