Pentacoordinated phosphorus as the internucleoside linkage : synthesis and phosphorus-31 NMR study of the pseudorotational dynamics

L.H. Koole; H.M. Moody; H.M. Buck

doi:10.1002/recl.19861050608

Pentacoordinated phosphorus as the internucleoside linkage : synthesis and phosphorus-31 NMR study of the pseudorotational dynamics

L.H. Koole, H.M. Moody, H.M. Buck

Chemical Engineering and Chemistry

Research output: Contribution to journal › Article › Academic › peer-review

5 Citations (Scopus)

Abstract

The synthesis of the first dinucleotide with a pentacoordinated phosphorus as the internucleoside linkage is described. 31P-NMR measurements revealed that the phosphorus pseudorotation proceeds with rapid stereomutation.

Original language	English
Pages (from-to)	196-197
Journal	Recueil des Travaux Chimiques des Pays-Bas
Volume	105
Issue number	6
DOIs	https://doi.org/10.1002/recl.19861050608
Publication status	Published - 1986

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title = "Pentacoordinated phosphorus as the internucleoside linkage : synthesis and phosphorus-31 NMR study of the pseudorotational dynamics",

abstract = "The synthesis of the first dinucleotide with a pentacoordinated phosphorus as the internucleoside linkage is described. 31P-NMR measurements revealed that the phosphorus pseudorotation proceeds with rapid stereomutation.",

author = "L.H. Koole and H.M. Moody and H.M. Buck",

year = "1986",

doi = "10.1002/recl.19861050608",

language = "English",

volume = "105",

pages = "196--197",

journal = "Recueil des Travaux Chimiques des Pays-Bas",

issn = "0165-0513",

publisher = "Royal Netherlands Chemical Society",

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T1 - Pentacoordinated phosphorus as the internucleoside linkage : synthesis and phosphorus-31 NMR study of the pseudorotational dynamics

AU - Koole, L.H.

AU - Moody, H.M.

AU - Buck, H.M.

PY - 1986

Y1 - 1986

N2 - The synthesis of the first dinucleotide with a pentacoordinated phosphorus as the internucleoside linkage is described. 31P-NMR measurements revealed that the phosphorus pseudorotation proceeds with rapid stereomutation.

AB - The synthesis of the first dinucleotide with a pentacoordinated phosphorus as the internucleoside linkage is described. 31P-NMR measurements revealed that the phosphorus pseudorotation proceeds with rapid stereomutation.

U2 - 10.1002/recl.19861050608

DO - 10.1002/recl.19861050608

M3 - Article

SN - 0165-0513

VL - 105

SP - 196

EP - 197

JO - Recueil des Travaux Chimiques des Pays-Bas

JF - Recueil des Travaux Chimiques des Pays-Bas

IS - 6

ER -

Pentacoordinated phosphorus as the internucleoside linkage : synthesis and phosphorus-31 NMR study of the pseudorotational dynamics

Abstract

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