Particle growth in butadiene emulsion polymerization. 3. Radical adsorption and desorption rate coefficients

E.M.F.J. Verdurmen; J.M. Geurts; A.L. German

doi:10.1002/macp.1994.021950221

Particle growth in butadiene emulsion polymerization. 3. Radical adsorption and desorption rate coefficients

E.M.F.J. Verdurmen
, J.M. Geurts
, A.L. German

Chemical Engineering and Chemistry

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Abstract

The kinetics of the emulsion polymn. of butadiene at 60 Deg in Smith-Ewart interval III were investigated using peroxodisulfate as initiator. The aim of this work was to obtain insight in the radical adsorption and desorption rate coeffs. through monitoring non-steady-state kinetics. The acquired data shows an initiator concn. dependence of the desorption-rate coeffs. This dependence explains the independence of the rate of butadiene emulsion polymn. of the peroxodisulfate concn. in the presence of tertiary dodecylthiols

Original language	English
Pages (from-to)	641-645
Journal	Macromolecular Chemistry and Physics
Volume	195
Issue number	2
DOIs	https://doi.org/10.1002/macp.1994.021950221
Publication status	Published - 1994

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abstract = "The kinetics of the emulsion polymn. of butadiene at 60 Deg in Smith-Ewart interval III were investigated using peroxodisulfate as initiator. The aim of this work was to obtain insight in the radical adsorption and desorption rate coeffs. through monitoring non-steady-state kinetics. The acquired data shows an initiator concn. dependence of the desorption-rate coeffs. This dependence explains the independence of the rate of butadiene emulsion polymn. of the peroxodisulfate concn. in the presence of tertiary dodecylthiols",

author = "E.M.F.J. Verdurmen and J.M. Geurts and A.L. German",

year = "1994",

doi = "10.1002/macp.1994.021950221",

language = "English",

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journal = "Macromolecular Chemistry and Physics",

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T1 - Particle growth in butadiene emulsion polymerization. 3. Radical adsorption and desorption rate coefficients

AU - Verdurmen, E.M.F.J.

AU - Geurts, J.M.

AU - German, A.L.

PY - 1994

Y1 - 1994

N2 - The kinetics of the emulsion polymn. of butadiene at 60 Deg in Smith-Ewart interval III were investigated using peroxodisulfate as initiator. The aim of this work was to obtain insight in the radical adsorption and desorption rate coeffs. through monitoring non-steady-state kinetics. The acquired data shows an initiator concn. dependence of the desorption-rate coeffs. This dependence explains the independence of the rate of butadiene emulsion polymn. of the peroxodisulfate concn. in the presence of tertiary dodecylthiols

AB - The kinetics of the emulsion polymn. of butadiene at 60 Deg in Smith-Ewart interval III were investigated using peroxodisulfate as initiator. The aim of this work was to obtain insight in the radical adsorption and desorption rate coeffs. through monitoring non-steady-state kinetics. The acquired data shows an initiator concn. dependence of the desorption-rate coeffs. This dependence explains the independence of the rate of butadiene emulsion polymn. of the peroxodisulfate concn. in the presence of tertiary dodecylthiols

U2 - 10.1002/macp.1994.021950221

DO - 10.1002/macp.1994.021950221

M3 - Article

SN - 1022-1352

VL - 195

SP - 641

EP - 645

JO - Macromolecular Chemistry and Physics

JF - Macromolecular Chemistry and Physics

IS - 2

ER -

Particle growth in butadiene emulsion polymerization. 3. Radical adsorption and desorption rate coefficients

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