TY - JOUR
T1 - Parameters affecting the synthesis of titanium silicalite 1
AU - vd Pol, A.J.H.P.
AU - Hooff, van, J.H.C.
PY - 1992
Y1 - 1992
N2 - For prepn. of zeolite TS-1, the influence of the SiO2 source, crystn. time, stirred/static crystn. conditions, TPAOH source, OH-/Si ratio, Si/Ti ratio and sol concn. were studied. Crystns. were carried out at 175 Deg in Teflon-lined autoclaves. Well shaped, homogeneous, highly cryst. batches of TS-1 zeolites were prepd. with Si/Ti ratio 24 to ... (0 to 4 mol-% Ti) and a crystallite size of 0.09-12 mm. To form small crystallites, seeds are added and the reaction mixt. is agitated during crystn. The best conditions to form small crystallites are: high silicon concn., low OH- concn. and low water concn. [on SciFinder (R)]
AB - For prepn. of zeolite TS-1, the influence of the SiO2 source, crystn. time, stirred/static crystn. conditions, TPAOH source, OH-/Si ratio, Si/Ti ratio and sol concn. were studied. Crystns. were carried out at 175 Deg in Teflon-lined autoclaves. Well shaped, homogeneous, highly cryst. batches of TS-1 zeolites were prepd. with Si/Ti ratio 24 to ... (0 to 4 mol-% Ti) and a crystallite size of 0.09-12 mm. To form small crystallites, seeds are added and the reaction mixt. is agitated during crystn. The best conditions to form small crystallites are: high silicon concn., low OH- concn. and low water concn. [on SciFinder (R)]
U2 - 10.1016/0926-860X(92)80309-Z
DO - 10.1016/0926-860X(92)80309-Z
M3 - Article
SN - 0926-860X
VL - 92
SP - 93
EP - 111
JO - Applied Catalysis. A, General
JF - Applied Catalysis. A, General
IS - 2
ER -