Parallel kinetic investigation of 2-oxazoline polymerizations with different initiators as basis for designed copolymer synthesis

R. Hoogenboom; M.W.M. Fijten; U.S. Schubert

doi:10.1002/pola.20024

Parallel kinetic investigation of 2-oxazoline polymerizations with different initiators as basis for designed copolymer synthesis

R. Hoogenboom, M.W.M. Fijten, U.S. Schubert

Chemical Engineering and Chemistry

Research output: Contribution to journal › Article › Academic › peer-review

95 Citations (Scopus)

Abstract

The systematical kinetic investigations of 4 2-substituted-2-oxazoline monomers with 4 initiators at 2 temps. and four monomer/initiator ratios are described. To cover this broad range of variables (128 different combinations), an automated synthesizer was used to accelerate the investigations and to provide highly comparable results. With both gas chromatog. and gel permeation chromatog., the livingness and the polymn. rates were detd. for the different polymns. The resulting insights in the kinetics were used for the directed synthesis of truly random copolymers and copolymers with compn. drift

Original language	English
Pages (from-to)	1830-1840
Journal	Journal of Polymer Science, Part A: Polymer Chemistry
Volume	42
Issue number	8
DOIs	https://doi.org/10.1002/pola.20024
Publication status	Published - 2004

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title = "Parallel kinetic investigation of 2-oxazoline polymerizations with different initiators as basis for designed copolymer synthesis",

abstract = "The systematical kinetic investigations of 4 2-substituted-2-oxazoline monomers with 4 initiators at 2 temps. and four monomer/initiator ratios are described. To cover this broad range of variables (128 different combinations), an automated synthesizer was used to accelerate the investigations and to provide highly comparable results. With both gas chromatog. and gel permeation chromatog., the livingness and the polymn. rates were detd. for the different polymns. The resulting insights in the kinetics were used for the directed synthesis of truly random copolymers and copolymers with compn. drift",

author = "R. Hoogenboom and M.W.M. Fijten and U.S. Schubert",

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AU - Schubert, U.S.

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N2 - The systematical kinetic investigations of 4 2-substituted-2-oxazoline monomers with 4 initiators at 2 temps. and four monomer/initiator ratios are described. To cover this broad range of variables (128 different combinations), an automated synthesizer was used to accelerate the investigations and to provide highly comparable results. With both gas chromatog. and gel permeation chromatog., the livingness and the polymn. rates were detd. for the different polymns. The resulting insights in the kinetics were used for the directed synthesis of truly random copolymers and copolymers with compn. drift

AB - The systematical kinetic investigations of 4 2-substituted-2-oxazoline monomers with 4 initiators at 2 temps. and four monomer/initiator ratios are described. To cover this broad range of variables (128 different combinations), an automated synthesizer was used to accelerate the investigations and to provide highly comparable results. With both gas chromatog. and gel permeation chromatog., the livingness and the polymn. rates were detd. for the different polymns. The resulting insights in the kinetics were used for the directed synthesis of truly random copolymers and copolymers with compn. drift

U2 - 10.1002/pola.20024

DO - 10.1002/pola.20024

M3 - Article

VL - 42

SP - 1830

EP - 1840

JO - Journal of Polymer Science, Part A: Polymer Chemistry

JF - Journal of Polymer Science, Part A: Polymer Chemistry

SN - 0887-624X

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