Oxidative drying of alkyd paints catalysed by a dinuclear manganese complex (MnMeTACN)

Z.O. Oyman; W. Ming; R. Linde, van der; J. Borg, ter; A. Schut; J.H. Bieleman

doi:10.1007/BF02699583

Oxidative drying of alkyd paints catalysed by a dinuclear manganese complex (MnMeTACN)

Z.O. Oyman, W. Ming, R. Linde, van der, J. Borg, ter, A. Schut, J.H. Bieleman

Materials and Interface Chemistry

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Abstract

The application of a dinuclear manganese complex (MnMeTACN) as a catalyst in the oxidative drying of alkyd coatings is described. Experimental results on the film properties (drying time and film hardness) for various solvent- and water-borne alkyd coatings demonstrate that MnMeTACN is a potential alternative for commercially-available Co- and Mn-based catalysts. MnMeTACN appears to be suitable for both water-borne and solvent-borne alkyd systems. Confocal Raman microscopy is used to study the depth profile of the drying of alkyd coatings catalysed by different catalysts, and it has been found that slow surface drying is somewhat compensated by relatively fast deep layer drying.

Original language	English
Pages (from-to)	269-275
Number of pages	7
Journal	Surface Coatings International Part B: Coatings Transactions
Volume	88
Issue number	4
DOIs	https://doi.org/10.1007/BF02699583
Publication status	Published - 2005

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title = "Oxidative drying of alkyd paints catalysed by a dinuclear manganese complex (MnMeTACN)",

abstract = "The application of a dinuclear manganese complex (MnMeTACN) as a catalyst in the oxidative drying of alkyd coatings is described. Experimental results on the film properties (drying time and film hardness) for various solvent- and water-borne alkyd coatings demonstrate that MnMeTACN is a potential alternative for commercially-available Co- and Mn-based catalysts. MnMeTACN appears to be suitable for both water-borne and solvent-borne alkyd systems. Confocal Raman microscopy is used to study the depth profile of the drying of alkyd coatings catalysed by different catalysts, and it has been found that slow surface drying is somewhat compensated by relatively fast deep layer drying.",

author = "Z.O. Oyman and W. Ming and {Linde, van der}, R. and {Borg, ter}, J. and A. Schut and J.H. Bieleman",

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T1 - Oxidative drying of alkyd paints catalysed by a dinuclear manganese complex (MnMeTACN)

AU - Oyman, Z.O.

AU - Ming, W.

AU - Linde, van der, R.

AU - Borg, ter, J.

AU - Schut, A.

AU - Bieleman, J.H.

PY - 2005

Y1 - 2005

N2 - The application of a dinuclear manganese complex (MnMeTACN) as a catalyst in the oxidative drying of alkyd coatings is described. Experimental results on the film properties (drying time and film hardness) for various solvent- and water-borne alkyd coatings demonstrate that MnMeTACN is a potential alternative for commercially-available Co- and Mn-based catalysts. MnMeTACN appears to be suitable for both water-borne and solvent-borne alkyd systems. Confocal Raman microscopy is used to study the depth profile of the drying of alkyd coatings catalysed by different catalysts, and it has been found that slow surface drying is somewhat compensated by relatively fast deep layer drying.

AB - The application of a dinuclear manganese complex (MnMeTACN) as a catalyst in the oxidative drying of alkyd coatings is described. Experimental results on the film properties (drying time and film hardness) for various solvent- and water-borne alkyd coatings demonstrate that MnMeTACN is a potential alternative for commercially-available Co- and Mn-based catalysts. MnMeTACN appears to be suitable for both water-borne and solvent-borne alkyd systems. Confocal Raman microscopy is used to study the depth profile of the drying of alkyd coatings catalysed by different catalysts, and it has been found that slow surface drying is somewhat compensated by relatively fast deep layer drying.

U2 - 10.1007/BF02699583

DO - 10.1007/BF02699583

M3 - Article

SN - 1476-4865

VL - 88

SP - 269

EP - 275

JO - Surface Coatings International Part B: Coatings Transactions

JF - Surface Coatings International Part B: Coatings Transactions

IS - 4

ER -

Oxidative drying of alkyd paints catalysed by a dinuclear manganese complex (MnMeTACN)

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