Oxidation state of platinum in oxidative-addition reactions and eta1-iodine products from dihalogen reactions with organoplatinum(II) complexes, as inferred from monochromatic X-ray photoelectron spectroscopy

J.C. Muijsers, J.W. Niemantsverdriet, I.C.M. Wehman-Ooyevaar, D.M. Grove, G. Koten, van

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Abstract

XPS indicates that the organometallic compd. [PtI[C6H3(CH2NMe2)2-2,6](h1-I2)], (I), representing an end-on coordinated dihalogen intermediate in the oxidative addn. reaction of dihalogen to d8 metal centers, contains platinum in a divalent oxidn. state. The use of a monochromatized x-ray source, short measurement times, and a cooled sample are essential to avoid sample degrdn. [on SciFinder (R)]
Original languageEnglish
Pages (from-to)2655-2658
JournalInorganic Chemistry
Volume31
Issue number12
DOIs
Publication statusPublished - 1992

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Addition reactions
Organometallics
Platinum
Time measurement
Iodine
iodine
platinum
X ray photoelectron spectroscopy
Metals
photoelectron spectroscopy
X rays
Oxidation
oxidation
x ray sources
products
x rays
time measurement
metals

Cite this

@article{7078f79a188c43f29f47c6fd45db5f8a,
title = "Oxidation state of platinum in oxidative-addition reactions and eta1-iodine products from dihalogen reactions with organoplatinum(II) complexes, as inferred from monochromatic X-ray photoelectron spectroscopy",
abstract = "XPS indicates that the organometallic compd. [PtI[C6H3(CH2NMe2)2-2,6](h1-I2)], (I), representing an end-on coordinated dihalogen intermediate in the oxidative addn. reaction of dihalogen to d8 metal centers, contains platinum in a divalent oxidn. state. The use of a monochromatized x-ray source, short measurement times, and a cooled sample are essential to avoid sample degrdn. [on SciFinder (R)]",
author = "J.C. Muijsers and J.W. Niemantsverdriet and I.C.M. Wehman-Ooyevaar and D.M. Grove and {Koten, van}, G.",
year = "1992",
doi = "10.1021/ic00038a064",
language = "English",
volume = "31",
pages = "2655--2658",
journal = "Inorganic Chemistry",
issn = "0020-1669",
publisher = "American Chemical Society",
number = "12",

}

Oxidation state of platinum in oxidative-addition reactions and eta1-iodine products from dihalogen reactions with organoplatinum(II) complexes, as inferred from monochromatic X-ray photoelectron spectroscopy. / Muijsers, J.C.; Niemantsverdriet, J.W.; Wehman-Ooyevaar, I.C.M.; Grove, D.M.; Koten, van, G.

In: Inorganic Chemistry, Vol. 31, No. 12, 1992, p. 2655-2658.

Research output: Contribution to journalArticleAcademicpeer-review

TY - JOUR

T1 - Oxidation state of platinum in oxidative-addition reactions and eta1-iodine products from dihalogen reactions with organoplatinum(II) complexes, as inferred from monochromatic X-ray photoelectron spectroscopy

AU - Muijsers, J.C.

AU - Niemantsverdriet, J.W.

AU - Wehman-Ooyevaar, I.C.M.

AU - Grove, D.M.

AU - Koten, van, G.

PY - 1992

Y1 - 1992

N2 - XPS indicates that the organometallic compd. [PtI[C6H3(CH2NMe2)2-2,6](h1-I2)], (I), representing an end-on coordinated dihalogen intermediate in the oxidative addn. reaction of dihalogen to d8 metal centers, contains platinum in a divalent oxidn. state. The use of a monochromatized x-ray source, short measurement times, and a cooled sample are essential to avoid sample degrdn. [on SciFinder (R)]

AB - XPS indicates that the organometallic compd. [PtI[C6H3(CH2NMe2)2-2,6](h1-I2)], (I), representing an end-on coordinated dihalogen intermediate in the oxidative addn. reaction of dihalogen to d8 metal centers, contains platinum in a divalent oxidn. state. The use of a monochromatized x-ray source, short measurement times, and a cooled sample are essential to avoid sample degrdn. [on SciFinder (R)]

U2 - 10.1021/ic00038a064

DO - 10.1021/ic00038a064

M3 - Article

VL - 31

SP - 2655

EP - 2658

JO - Inorganic Chemistry

JF - Inorganic Chemistry

SN - 0020-1669

IS - 12

ER -