Oxidation state of platinum in oxidative-addition reactions and eta1-iodine products from dihalogen reactions with organoplatinum(II) complexes, as inferred from monochromatic X-ray photoelectron spectroscopy

J.C. Muijsers; J.W. Niemantsverdriet; I.C.M. Wehman-Ooyevaar; D.M. Grove; G. Koten, van

doi:10.1021/ic00038a064

Oxidation state of platinum in oxidative-addition reactions and eta1-iodine products from dihalogen reactions with organoplatinum(II) complexes, as inferred from monochromatic X-ray photoelectron spectroscopy

J.C. Muijsers, J.W. Niemantsverdriet, I.C.M. Wehman-Ooyevaar, D.M. Grove, G. Koten, van

Inorganic Materials & Catalysis

Research output: Contribution to journal › Article › Academic › peer-review

27 Citations (Scopus)

177 Downloads (Pure)

Abstract

XPS indicates that the organometallic compd. [PtI[C6H3(CH2NMe2)2-2,6](h1-I2)], (I), representing an end-on coordinated dihalogen intermediate in the oxidative addn. reaction of dihalogen to d8 metal centers, contains platinum in a divalent oxidn. state. The use of a monochromatized x-ray source, short measurement times, and a cooled sample are essential to avoid sample degrdn. [on SciFinder (R)]

Original language	English
Pages (from-to)	2655-2658
Journal	Inorganic Chemistry
Volume	31
Issue number	12
DOIs	https://doi.org/10.1021/ic00038a064
Publication status	Published - 1992

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Muijsers, J. C., Niemantsverdriet, J. W., Wehman-Ooyevaar, I. C. M., Grove, D. M., & Koten, van, G. (1992). Oxidation state of platinum in oxidative-addition reactions and eta1-iodine products from dihalogen reactions with organoplatinum(II) complexes, as inferred from monochromatic X-ray photoelectron spectroscopy. Inorganic Chemistry, 31(12), 2655-2658. https://doi.org/10.1021/ic00038a064

@article{7078f79a188c43f29f47c6fd45db5f8a,

title = "Oxidation state of platinum in oxidative-addition reactions and eta1-iodine products from dihalogen reactions with organoplatinum(II) complexes, as inferred from monochromatic X-ray photoelectron spectroscopy",

abstract = "XPS indicates that the organometallic compd. [PtI[C6H3(CH2NMe2)2-2,6](h1-I2)], (I), representing an end-on coordinated dihalogen intermediate in the oxidative addn. reaction of dihalogen to d8 metal centers, contains platinum in a divalent oxidn. state. The use of a monochromatized x-ray source, short measurement times, and a cooled sample are essential to avoid sample degrdn. [on SciFinder (R)]",

author = "J.C. Muijsers and J.W. Niemantsverdriet and I.C.M. Wehman-Ooyevaar and D.M. Grove and {Koten, van}, G.",

year = "1992",

doi = "10.1021/ic00038a064",

language = "English",

volume = "31",

pages = "2655--2658",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "12",

}

Muijsers, JC, Niemantsverdriet, JW, Wehman-Ooyevaar, ICM, Grove, DM & Koten, van, G 1992, 'Oxidation state of platinum in oxidative-addition reactions and eta1-iodine products from dihalogen reactions with organoplatinum(II) complexes, as inferred from monochromatic X-ray photoelectron spectroscopy', Inorganic Chemistry, vol. 31, no. 12, pp. 2655-2658. https://doi.org/10.1021/ic00038a064

Oxidation state of platinum in oxidative-addition reactions and eta1-iodine products from dihalogen reactions with organoplatinum(II) complexes, as inferred from monochromatic X-ray photoelectron spectroscopy. / Muijsers, J.C.; Niemantsverdriet, J.W.; Wehman-Ooyevaar, I.C.M. et al.
In: Inorganic Chemistry, Vol. 31, No. 12, 1992, p. 2655-2658.

Research output: Contribution to journal › Article › Academic › peer-review

TY - JOUR

T1 - Oxidation state of platinum in oxidative-addition reactions and eta1-iodine products from dihalogen reactions with organoplatinum(II) complexes, as inferred from monochromatic X-ray photoelectron spectroscopy

AU - Muijsers, J.C.

AU - Niemantsverdriet, J.W.

AU - Wehman-Ooyevaar, I.C.M.

AU - Grove, D.M.

AU - Koten, van, G.

PY - 1992

Y1 - 1992

N2 - XPS indicates that the organometallic compd. [PtI[C6H3(CH2NMe2)2-2,6](h1-I2)], (I), representing an end-on coordinated dihalogen intermediate in the oxidative addn. reaction of dihalogen to d8 metal centers, contains platinum in a divalent oxidn. state. The use of a monochromatized x-ray source, short measurement times, and a cooled sample are essential to avoid sample degrdn. [on SciFinder (R)]

AB - XPS indicates that the organometallic compd. [PtI[C6H3(CH2NMe2)2-2,6](h1-I2)], (I), representing an end-on coordinated dihalogen intermediate in the oxidative addn. reaction of dihalogen to d8 metal centers, contains platinum in a divalent oxidn. state. The use of a monochromatized x-ray source, short measurement times, and a cooled sample are essential to avoid sample degrdn. [on SciFinder (R)]

U2 - 10.1021/ic00038a064

DO - 10.1021/ic00038a064

M3 - Article

SN - 0020-1669

VL - 31

SP - 2655

EP - 2658

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 12

ER -