TY - JOUR
T1 - Oxidation of glucose to k-gluconate II. Platinum-catalyzed oxidation with oxygen in aqueous alkaline solutions
AU - de Wilt, H.G.J.
AU - van der Baan, Hessel
PY - 1972
Y1 - 1972
N2 - Pt-catalyzed oxidn. of glucose to gluconate is studied in an oxygen-sparged batch reactor. In each expt. the reaction appears to be first order in glucose, and the rate const. is inversely proportional to the initial concn. of glucose. A kinetic model describing these exptl. observations is developed. The influence of the initial concns. of glucose, hydroxide ion, and O in the liq. phase, the concn. of catalyst, and temp. on the reaction-rate const. are described. The av. selectivity of the process is about 90%. [on SciFinder (R)]
AB - Pt-catalyzed oxidn. of glucose to gluconate is studied in an oxygen-sparged batch reactor. In each expt. the reaction appears to be first order in glucose, and the rate const. is inversely proportional to the initial concn. of glucose. A kinetic model describing these exptl. observations is developed. The influence of the initial concns. of glucose, hydroxide ion, and O in the liq. phase, the concn. of catalyst, and temp. on the reaction-rate const. are described. The av. selectivity of the process is about 90%. [on SciFinder (R)]
U2 - 10.1021/i360044a003
DO - 10.1021/i360044a003
M3 - Article
SN - 0019-7890
VL - 11
SP - 374
EP - 378
JO - Industrial and Engineering Chemistry. Product Research and Development
JF - Industrial and Engineering Chemistry. Product Research and Development
IS - 4
ER -