Oxidation of D-glucose and D-fructose with oxygen in aqueous, alkaline solutions. Part I. An integral reaction scheme

H.G.J. de Wilt; B.F.M. Kuster

doi:10.1016/S0008-6215(00)80307-9

Oxidation of D-glucose and D-fructose with oxygen in aqueous, alkaline solutions. Part I. An integral reaction scheme

H.G.J. de Wilt
, B.F.M. Kuster

Chemical Engineering and Chemistry

Research output: Contribution to journal › Article › Academic › peer-review

31 Citations (Scopus)

Abstract

The homogeneous oxidn. of D-glucose and D-fructose with O in aq., alk. solns. is studied, and a reaction scheme proposed to account for the obsd. reaction products. Formation of enolate anions is followed by non-oxidative reactions (involving double-bond migration and cleavage) and by oxidative formation of peroxides, leading to the formation, of D-arabinonic, D-erythronic, D-glyceric, glycolic, and formic acids. [on SciFinder (R)]

Original language	English
Pages (from-to)	5-15
Number of pages	11
Journal	Carbohydrate Research
Volume	19
Issue number	1
DOIs	https://doi.org/10.1016/S0008-6215(00)80307-9
Publication status	Published - 1971

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title = "Oxidation of D-glucose and D-fructose with oxygen in aqueous, alkaline solutions. Part I. An integral reaction scheme",

abstract = "The homogeneous oxidn. of D-glucose and D-fructose with O in aq., alk. solns. is studied, and a reaction scheme proposed to account for the obsd. reaction products. Formation of enolate anions is followed by non-oxidative reactions (involving double-bond migration and cleavage) and by oxidative formation of peroxides, leading to the formation, of D-arabinonic, D-erythronic, D-glyceric, glycolic, and formic acids. [on SciFinder (R)]",

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T1 - Oxidation of D-glucose and D-fructose with oxygen in aqueous, alkaline solutions. Part I. An integral reaction scheme

AU - de Wilt, H.G.J.

AU - Kuster, B.F.M.

PY - 1971

Y1 - 1971

N2 - The homogeneous oxidn. of D-glucose and D-fructose with O in aq., alk. solns. is studied, and a reaction scheme proposed to account for the obsd. reaction products. Formation of enolate anions is followed by non-oxidative reactions (involving double-bond migration and cleavage) and by oxidative formation of peroxides, leading to the formation, of D-arabinonic, D-erythronic, D-glyceric, glycolic, and formic acids. [on SciFinder (R)]

AB - The homogeneous oxidn. of D-glucose and D-fructose with O in aq., alk. solns. is studied, and a reaction scheme proposed to account for the obsd. reaction products. Formation of enolate anions is followed by non-oxidative reactions (involving double-bond migration and cleavage) and by oxidative formation of peroxides, leading to the formation, of D-arabinonic, D-erythronic, D-glyceric, glycolic, and formic acids. [on SciFinder (R)]

U2 - 10.1016/S0008-6215(00)80307-9

DO - 10.1016/S0008-6215(00)80307-9

M3 - Article

SN - 0008-6215

VL - 19

SP - 5

EP - 15

JO - Carbohydrate Research

JF - Carbohydrate Research

IS - 1

ER -

Oxidation of D-glucose and D-fructose with oxygen in aqueous, alkaline solutions. Part I. An integral reaction scheme

Abstract

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