TY - JOUR
T1 - Oxidation of D-glucose and D-fructose with oxygen in aqueous, alkaline solutions. III. Kinetic approach to the product distribution
AU - de Wilt, H.G.J.
AU - Kuster, Ben
PY - 1972
Y1 - 1972
N2 - Based on a previously reported, integral reaction-scheme for the homogeneous oxidation of -glucose and -fructose with oxygen in aqueous, alkaline solutions, a kinetic model covering the product distribution has been developed. The model consists of a repeated set of reactions with constant rate coefficients, starting from each enolate ion. The product distribution can be understood as a function of the temperature, the hydroxyl-ion concentration, and the oxygen concentration in the liquid phase.
AB - Based on a previously reported, integral reaction-scheme for the homogeneous oxidation of -glucose and -fructose with oxygen in aqueous, alkaline solutions, a kinetic model covering the product distribution has been developed. The model consists of a repeated set of reactions with constant rate coefficients, starting from each enolate ion. The product distribution can be understood as a function of the temperature, the hydroxyl-ion concentration, and the oxygen concentration in the liquid phase.
U2 - 10.1016/S0008-6215(00)82704-4
DO - 10.1016/S0008-6215(00)82704-4
M3 - Article
VL - 23
SP - 343
EP - 348
JO - Carbohydrate Research
JF - Carbohydrate Research
SN - 0008-6215
IS - 3
ER -