Oxidation of D-glucose and D-fructose with oxygen in aqueous, alkaline solutions. III. Kinetic approach to the product distribution

H.G.J. de Wilt; Ben Kuster

doi:10.1016/S0008-6215(00)82704-4

Oxidation of D-glucose and D-fructose with oxygen in aqueous, alkaline solutions. III. Kinetic approach to the product distribution

H.G.J. de Wilt, Ben Kuster

Chemical Engineering and Chemistry

Research output: Contribution to journal › Article › Academic › peer-review

7 Citations (Scopus)

Abstract

Based on a previously reported, integral reaction-scheme for the homogeneous oxidation of -glucose and -fructose with oxygen in aqueous, alkaline solutions, a kinetic model covering the product distribution has been developed. The model consists of a repeated set of reactions with constant rate coefficients, starting from each enolate ion. The product distribution can be understood as a function of the temperature, the hydroxyl-ion concentration, and the oxygen concentration in the liquid phase.

Original language	English
Pages (from-to)	343-348
Number of pages	6
Journal	Carbohydrate Research
Volume	23
Issue number	3
DOIs	https://doi.org/10.1016/S0008-6215(00)82704-4
Publication status	Published - 1972

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abstract = "Based on a previously reported, integral reaction-scheme for the homogeneous oxidation of -glucose and -fructose with oxygen in aqueous, alkaline solutions, a kinetic model covering the product distribution has been developed. The model consists of a repeated set of reactions with constant rate coefficients, starting from each enolate ion. The product distribution can be understood as a function of the temperature, the hydroxyl-ion concentration, and the oxygen concentration in the liquid phase.",

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AU - de Wilt, H.G.J.

AU - Kuster, Ben

PY - 1972

Y1 - 1972

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AB - Based on a previously reported, integral reaction-scheme for the homogeneous oxidation of -glucose and -fructose with oxygen in aqueous, alkaline solutions, a kinetic model covering the product distribution has been developed. The model consists of a repeated set of reactions with constant rate coefficients, starting from each enolate ion. The product distribution can be understood as a function of the temperature, the hydroxyl-ion concentration, and the oxygen concentration in the liquid phase.

U2 - 10.1016/S0008-6215(00)82704-4

DO - 10.1016/S0008-6215(00)82704-4

M3 - Article

VL - 23

SP - 343

EP - 348

JO - Carbohydrate Research

JF - Carbohydrate Research

SN - 0008-6215

IS - 3

ER -