Oxidation of CH4 by CO2 in a dielectric barrier discharge

L. M. Martini; G. Dilecce; G. Guella; A. Maranzana; G. Tonachini; P. Tosi

doi:10.1016/j.cplett.2013.12.069

Oxidation of CH₄ by CO₂ in a dielectric barrier discharge

L. M. Martini, G. Dilecce, G. Guella, A. Maranzana, G. Tonachini, P. Tosi

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Abstract

In the plasma dry reforming, CH₄ and CO₂ are dissociated by electron collisions producing fragments that in turn react to form new molecules. While the production of CO, H₂, and small hydrocarbons has been investigated extensively, much less is known about the plasma synthesis of oxygenated molecules, which is the target of the present work. In addition to experimental results, gas phase reactions for the production of acetic, formic and propanoic acid were investigated by DFT calculations.

Original language	English
Pages (from-to)	55-60
Number of pages	6
Journal	Chemical Physics Letters
Volume	593
DOIs	https://doi.org/10.1016/j.cplett.2013.12.069
Publication status	Published - 11 Feb 2014
Externally published	Yes

Funding

This Letter was partially supported by Provincia Autonoma di Trento and Istituto MCB of CNR (ENAM project). Appendix A

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abstract = "In the plasma dry reforming, CH4 and CO2 are dissociated by electron collisions producing fragments that in turn react to form new molecules. While the production of CO, H2, and small hydrocarbons has been investigated extensively, much less is known about the plasma synthesis of oxygenated molecules, which is the target of the present work. In addition to experimental results, gas phase reactions for the production of acetic, formic and propanoic acid were investigated by DFT calculations.",

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AU - Dilecce, G.

AU - Guella, G.

AU - Maranzana, A.

AU - Tonachini, G.

AU - Tosi, P.

PY - 2014/2/11

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N2 - In the plasma dry reforming, CH4 and CO2 are dissociated by electron collisions producing fragments that in turn react to form new molecules. While the production of CO, H2, and small hydrocarbons has been investigated extensively, much less is known about the plasma synthesis of oxygenated molecules, which is the target of the present work. In addition to experimental results, gas phase reactions for the production of acetic, formic and propanoic acid were investigated by DFT calculations.

AB - In the plasma dry reforming, CH4 and CO2 are dissociated by electron collisions producing fragments that in turn react to form new molecules. While the production of CO, H2, and small hydrocarbons has been investigated extensively, much less is known about the plasma synthesis of oxygenated molecules, which is the target of the present work. In addition to experimental results, gas phase reactions for the production of acetic, formic and propanoic acid were investigated by DFT calculations.

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Oxidation of CH₄ by CO₂ in a dielectric barrier discharge

Abstract

Funding

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