Overpotential analysis of alkaline and acidic alcohol electrolysers and optimized membrane-electrode assemblies

F.M. Sapountzi (Corresponding author), V. Di Palma, G. Zafeiropoulos, H. Penchev, M.A. Verheijen, M. Creatore, F. Ublekov, V. Sinigersky, W.M. Arnold Bik, H.O.A. Fredriksson, M.N. Tsampas, J.W. Niemantsverdriet

Research output: Contribution to journalArticleAcademicpeer-review

Abstract

Alcohol electrolysis using polymeric membrane electrolytes is a promising route for storing excess renewable energy in hydrogen, alternative to the thermodynamically limited water electrolysis. By properly choosing the ionic agent (i.e. H+ or OH) and the catalyst support, and by tuning the catalyst structure, we developed membrane-electrode-assemblies which are suitable for cost-effective and efficient alcohol electrolysis. Novel porous electrodes were prepared by Atomic Layer Deposition (ALD) of Pt on a TiO2-Ti web of microfibers and were interfaced to polymeric membranes with either H+ or OH conductivity. Our results suggest that alcohol electrolysis is more efficient using OH conducting membranes under appropriate operation conditions (high pH in anolyte solution). ALD enables better catalyst utilization while it appears that the TiO2-Ti substrate is an ideal alternative to the conventional carbon-based diffusion layers, due to its open structure. Overall, by using our developmental anodes instead of commercial porous electrodes, the performance of the alcohol electrolyser (normalized per mass of Pt) can be increased up to ~30 times.
Original languageEnglish
Pages (from-to)10163-10173
Number of pages11
JournalInternational Journal of Hydrogen Energy
Volume44
Issue number21
DOIs
Publication statusPublished - 23 Apr 2019

Fingerprint

electrolysis
Electrolysis
assemblies
alcohols
Alcohols
membranes
Membranes
Polymeric membranes
Electrodes
electrodes
Atomic layer deposition
atomic layer epitaxy
catalysts
microfibers
Catalysts
renewable energy
Catalyst supports
Anodes
anodes
Tuning

Keywords

  • Alcohol electrolysis
  • Atomic layer deposition
  • Hydrogen production
  • Hydroxyl ion-conducting polymer
  • Porous electrodes
  • Proton-conducting polymer

Cite this

Sapountzi, F.M. ; Di Palma, V. ; Zafeiropoulos, G. ; Penchev, H. ; Verheijen, M.A. ; Creatore, M. ; Ublekov, F. ; Sinigersky, V. ; Bik, W.M. Arnold ; Fredriksson, H.O.A. ; Tsampas, M.N. ; Niemantsverdriet, J.W. / Overpotential analysis of alkaline and acidic alcohol electrolysers and optimized membrane-electrode assemblies. In: International Journal of Hydrogen Energy. 2019 ; Vol. 44, No. 21. pp. 10163-10173.
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Overpotential analysis of alkaline and acidic alcohol electrolysers and optimized membrane-electrode assemblies. / Sapountzi, F.M. (Corresponding author); Di Palma, V.; Zafeiropoulos, G.; Penchev, H.; Verheijen, M.A.; Creatore, M.; Ublekov, F.; Sinigersky, V.; Bik, W.M. Arnold; Fredriksson, H.O.A.; Tsampas, M.N.; Niemantsverdriet, J.W.

In: International Journal of Hydrogen Energy, Vol. 44, No. 21, 23.04.2019, p. 10163-10173.

Research output: Contribution to journalArticleAcademicpeer-review

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AU - Penchev, H.

AU - Verheijen, M.A.

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AU - Bik, W.M. Arnold

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AU - Niemantsverdriet, J.W.

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