Ordered arrays of ferroelectric nanoparticles by pulsed laser deposition on PS-b-P4VP(PDP) supramolecule-based templates

W. Zoelen, van; A.H.G. Vlooswijk; A. Ferri; A. Andringa; B. Noheda; G. Brinke, ten

doi:10.1021/cm901812j

Ordered arrays of ferroelectric nanoparticles by pulsed laser deposition on PS-b-P4VP(PDP) supramolecule-based templates

W. Zoelen, van, A.H.G. Vlooswijk, A. Ferri, A. Andringa, B. Noheda, G. Brinke, ten

Plasma & Materials Processing

Research output: Contribution to journal › Article › Academic › peer-review

15 Citations (Scopus)

Abstract

Thin films of comb-shaped supramolecules have been used to create arrays of spatially separated ordered nanorods with a polystyrene core and a poly(4-vinyl pyridine) corona. Room temperature pulsed laser deposition of a uniform layer of lead titanate on top of these nanorod arrays and Subsequent heating to 565 degrees C, far above the degradation temperature of the block copolymer nanorods, resulted in ordered arrays of ferroelectric lead titanate nanoparticles, due to the evaporation of the polymer rods and the SrTiO3 substrate-nucleated crystallization of the lead titanate. The spacing in between the ordered cylinders of the template and the nonselective nature of the coating procedure sets the method apart from conventional block copolymer templating techniques involving parallel cylindrical structures. Given the nonselective nature of the coating method, this template procedure is applicable for a large variety of inorganics.

Original language	English
Pages (from-to)	4719-4723
Number of pages	5
Journal	Chemistry of Materials
Volume	21
Issue number	19
DOIs	https://doi.org/10.1021/cm901812j
Publication status	Published - 2009

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title = "Ordered arrays of ferroelectric nanoparticles by pulsed laser deposition on PS-b-P4VP(PDP) supramolecule-based templates",

abstract = "Thin films of comb-shaped supramolecules have been used to create arrays of spatially separated ordered nanorods with a polystyrene core and a poly(4-vinyl pyridine) corona. Room temperature pulsed laser deposition of a uniform layer of lead titanate on top of these nanorod arrays and Subsequent heating to 565 degrees C, far above the degradation temperature of the block copolymer nanorods, resulted in ordered arrays of ferroelectric lead titanate nanoparticles, due to the evaporation of the polymer rods and the SrTiO3 substrate-nucleated crystallization of the lead titanate. The spacing in between the ordered cylinders of the template and the nonselective nature of the coating procedure sets the method apart from conventional block copolymer templating techniques involving parallel cylindrical structures. Given the nonselective nature of the coating method, this template procedure is applicable for a large variety of inorganics.",

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T1 - Ordered arrays of ferroelectric nanoparticles by pulsed laser deposition on PS-b-P4VP(PDP) supramolecule-based templates

AU - Zoelen, van, W.

AU - Vlooswijk, A.H.G.

AU - Ferri, A.

AU - Andringa, A.

AU - Noheda, B.

AU - Brinke, ten, G.

PY - 2009

Y1 - 2009

N2 - Thin films of comb-shaped supramolecules have been used to create arrays of spatially separated ordered nanorods with a polystyrene core and a poly(4-vinyl pyridine) corona. Room temperature pulsed laser deposition of a uniform layer of lead titanate on top of these nanorod arrays and Subsequent heating to 565 degrees C, far above the degradation temperature of the block copolymer nanorods, resulted in ordered arrays of ferroelectric lead titanate nanoparticles, due to the evaporation of the polymer rods and the SrTiO3 substrate-nucleated crystallization of the lead titanate. The spacing in between the ordered cylinders of the template and the nonselective nature of the coating procedure sets the method apart from conventional block copolymer templating techniques involving parallel cylindrical structures. Given the nonselective nature of the coating method, this template procedure is applicable for a large variety of inorganics.

AB - Thin films of comb-shaped supramolecules have been used to create arrays of spatially separated ordered nanorods with a polystyrene core and a poly(4-vinyl pyridine) corona. Room temperature pulsed laser deposition of a uniform layer of lead titanate on top of these nanorod arrays and Subsequent heating to 565 degrees C, far above the degradation temperature of the block copolymer nanorods, resulted in ordered arrays of ferroelectric lead titanate nanoparticles, due to the evaporation of the polymer rods and the SrTiO3 substrate-nucleated crystallization of the lead titanate. The spacing in between the ordered cylinders of the template and the nonselective nature of the coating procedure sets the method apart from conventional block copolymer templating techniques involving parallel cylindrical structures. Given the nonselective nature of the coating method, this template procedure is applicable for a large variety of inorganics.

UR - http://pubs.acs.org/doi/abs/10.1021/cm901812j

U2 - 10.1021/cm901812j

DO - 10.1021/cm901812j

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SN - 0897-4756

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JO - Chemistry of Materials

JF - Chemistry of Materials

IS - 19

ER -

Ordered arrays of ferroelectric nanoparticles by pulsed laser deposition on PS-b-P4VP(PDP) supramolecule-based templates

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