Optimization of the elution range in micellar electrokinetic capillary chromatography

W.G.H.M. Muijselaar; H.A. Claessens; C.A.M.G. Cramers

Optimization of the elution range in micellar electrokinetic capillary chromatography

W.G.H.M. Muijselaar
, H.A. Claessens
, C.A.M.G. Cramers

Chemical Engineering and Chemistry

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › Academic

Abstract

The resolution of neutra! solutes in micellar electrokinetic capillary chromatagrophy is influenced by the migration time of the electroosmotie flow, tEoF' the migration time of the micelles, tMe, and the capacity factors of the solutes, k. The resolution of a separation can be improved by increasing the elution window and by optimizing the capacity factors of the solutes. The influence of the buffer pH, surfactant concentration and organic modifier content of the electrolyte system on both the elution window and the capacity factors was investigated.

Original language	English
Title of host publication	15th International Symposium on Capillary Chromatography, Riva del Garda
Editors	P. Sandra, G. Devos
Place of Publication	Heidelberg
Publisher	Hüthig
Pages	1469-1476
Publication status	Published - 1993

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title = "Optimization of the elution range in micellar electrokinetic capillary chromatography",

abstract = "The resolution of neutra! solutes in micellar electrokinetic capillary chromatagrophy is influenced by the migration time of the electroosmotie flow, tEoF' the migration time of the micelles, tMe, and the capacity factors of the solutes, k. The resolution of a separation can be improved by increasing the elution window and by optimizing the capacity factors of the solutes. The influence of the buffer pH, surfactant concentration and organic modifier content of the electrolyte system on both the elution window and the capacity factors was investigated.",

author = "W.G.H.M. Muijselaar and H.A. Claessens and C.A.M.G. Cramers",

year = "1993",

language = "English",

pages = "1469--1476",

editor = "P. Sandra and G. Devos",

booktitle = "15th International Symposium on Capillary Chromatography, Riva del Garda",

publisher = "H{\"u}thig",

address = "Germany",

}

Optimization of the elution range in micellar electrokinetic capillary chromatography. / Muijselaar, W.G.H.M.; Claessens, H.A.; Cramers, C.A.M.G.
15th International Symposium on Capillary Chromatography, Riva del Garda. ed. / P. Sandra; G. Devos. Heidelberg: Hüthig, 1993. p. 1469-1476.

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › Academic

TY - GEN

T1 - Optimization of the elution range in micellar electrokinetic capillary chromatography

AU - Muijselaar, W.G.H.M.

AU - Claessens, H.A.

AU - Cramers, C.A.M.G.

PY - 1993

Y1 - 1993

N2 - The resolution of neutra! solutes in micellar electrokinetic capillary chromatagrophy is influenced by the migration time of the electroosmotie flow, tEoF' the migration time of the micelles, tMe, and the capacity factors of the solutes, k. The resolution of a separation can be improved by increasing the elution window and by optimizing the capacity factors of the solutes. The influence of the buffer pH, surfactant concentration and organic modifier content of the electrolyte system on both the elution window and the capacity factors was investigated.

AB - The resolution of neutra! solutes in micellar electrokinetic capillary chromatagrophy is influenced by the migration time of the electroosmotie flow, tEoF' the migration time of the micelles, tMe, and the capacity factors of the solutes, k. The resolution of a separation can be improved by increasing the elution window and by optimizing the capacity factors of the solutes. The influence of the buffer pH, surfactant concentration and organic modifier content of the electrolyte system on both the elution window and the capacity factors was investigated.

M3 - Conference contribution

SP - 1469

EP - 1476

BT - 15th International Symposium on Capillary Chromatography, Riva del Garda

A2 - Sandra, P.

A2 - Devos, G.

PB - Hüthig

CY - Heidelberg

ER -

Optimization of the elution range in micellar electrokinetic capillary chromatography

Abstract

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