Optical activity of chiral dendritic surfaces

J.F.G.A. Jansen; H.W.I. Peerlings; E.M.M. Brabander-van den Berg, de; E.W. Meijer

doi:10.1002/anie.199512061

Optical activity of chiral dendritic surfaces

J.F.G.A. Jansen
, H.W.I. Peerlings
, E.M.M. Brabander-van den Berg, de
, E.W. Meijer

Research output: Contribution to journal › Article › Academic › peer-review

122 Citations (Scopus)

332 Downloads (Pure)

Abstract

The optical rotation of poly(propylene imine) dendrimers with 64 identical enantiomerically pure amino acid end groups tends to zero. This remarkable behavior results from the packing of the end groups in the highly dense, multiply hydrogenbonded surface, which gives rise to different frozen-in conformations, leading to an internal compensation of optical activity.

Original language	English
Pages (from-to)	1206-1209
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	34
Issue number	11
DOIs	https://doi.org/10.1002/anie.199512061
Publication status	Published - 1995

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title = "Optical activity of chiral dendritic surfaces",

abstract = "The optical rotation of poly(propylene imine) dendrimers with 64 identical enantiomerically pure amino acid end groups tends to zero. This remarkable behavior results from the packing of the end groups in the highly dense, multiply hydrogenbonded surface, which gives rise to different frozen-in conformations, leading to an internal compensation of optical activity.",

author = "J.F.G.A. Jansen and H.W.I. Peerlings and \{Brabander-van den Berg, de\}, E.M.M. and E.W. Meijer",

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AU - Jansen, J.F.G.A.

AU - Peerlings, H.W.I.

AU - Brabander-van den Berg, de, E.M.M.

AU - Meijer, E.W.

PY - 1995

Y1 - 1995

N2 - The optical rotation of poly(propylene imine) dendrimers with 64 identical enantiomerically pure amino acid end groups tends to zero. This remarkable behavior results from the packing of the end groups in the highly dense, multiply hydrogenbonded surface, which gives rise to different frozen-in conformations, leading to an internal compensation of optical activity.

AB - The optical rotation of poly(propylene imine) dendrimers with 64 identical enantiomerically pure amino acid end groups tends to zero. This remarkable behavior results from the packing of the end groups in the highly dense, multiply hydrogenbonded surface, which gives rise to different frozen-in conformations, leading to an internal compensation of optical activity.

U2 - 10.1002/anie.199512061

DO - 10.1002/anie.199512061

M3 - Article

SN - 1433-7851

VL - 34

SP - 1206

EP - 1209

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 11

ER -

Optical activity of chiral dendritic surfaces

Abstract

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