On the second and third virial coefficient of methyl fluoride

R.J. Lunbeck; C.A. Seldam, ten

doi:10.1016/0031-8914(51)90100-0

On the second and third virial coefficient of methyl fluoride

R.J. Lunbeck, C.A. Seldam, ten

Research output: Contribution to journal › Article › Academic › peer-review

5 Citations (Scopus)

Abstract

Because of the polar character of methyl fluoride its virial coefficients cannot be described by a formula of the Lennard-Jones type for the molecular interaction. On extending this formula with a term, representing the dipole interaction, a good agreement was found between experimental and calculated values of the second and third virial coefficients. Only two constants had to be determined, the third constant occuring in the formula for the intermolecular field was taken from dielectric constant measurements.

Original language	English
Pages (from-to)	788-792
Journal	Physica
Volume	17
Issue number	8
DOIs	https://doi.org/10.1016/0031-8914(51)90100-0
Publication status	Published - 1951

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title = "On the second and third virial coefficient of methyl fluoride",

abstract = "Because of the polar character of methyl fluoride its virial coefficients cannot be described by a formula of the Lennard-Jones type for the molecular interaction. On extending this formula with a term, representing the dipole interaction, a good agreement was found between experimental and calculated values of the second and third virial coefficients. Only two constants had to be determined, the third constant occuring in the formula for the intermolecular field was taken from dielectric constant measurements.",

author = "R.J. Lunbeck and {Seldam, ten}, C.A.",

year = "1951",

doi = "10.1016/0031-8914(51)90100-0",

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TY - JOUR

T1 - On the second and third virial coefficient of methyl fluoride

AU - Lunbeck, R.J.

AU - Seldam, ten, C.A.

PY - 1951

Y1 - 1951

N2 - Because of the polar character of methyl fluoride its virial coefficients cannot be described by a formula of the Lennard-Jones type for the molecular interaction. On extending this formula with a term, representing the dipole interaction, a good agreement was found between experimental and calculated values of the second and third virial coefficients. Only two constants had to be determined, the third constant occuring in the formula for the intermolecular field was taken from dielectric constant measurements.

AB - Because of the polar character of methyl fluoride its virial coefficients cannot be described by a formula of the Lennard-Jones type for the molecular interaction. On extending this formula with a term, representing the dipole interaction, a good agreement was found between experimental and calculated values of the second and third virial coefficients. Only two constants had to be determined, the third constant occuring in the formula for the intermolecular field was taken from dielectric constant measurements.

U2 - 10.1016/0031-8914(51)90100-0

DO - 10.1016/0031-8914(51)90100-0

M3 - Article

SN - 0031-8914

VL - 17

SP - 788

EP - 792

JO - Physica

JF - Physica

IS - 8

ER -

On the second and third virial coefficient of methyl fluoride

Abstract

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