On the mechanism of polymerization of ε-caprolactam in the presence of water. III. Supplementary remarks on a previous paper. Introduction of volume correction

D. Heikens, P.H. Hermans

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    Abstract

    This paper is the third in this series and gives data and rate constants for the polymerization of ε-caprolactam in the presence of water, corrected for volume changes during reaction at 221.8°C. The influence of the experimental uncertainties of the reaction velocities at small reaction times is discussed.
    Original languageEnglish
    Pages (from-to)429-436
    Number of pages8
    JournalJournal of Polymer Science
    Volume44
    Issue number144
    DOIs
    Publication statusPublished - 1960

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