On the identification of 'co-sulfide' species in sulfided supported Co and CoMo catalysts

M.W.J. Crajé, V.H.J. Beer, de, J.A.R. Veen, van, A.M. Kraan, van der

Research output: Contribution to journalArticleAcademicpeer-review

5 Citations (Scopus)

Abstract

A review with 37 refs. Co-sulfide species formed in Co/C and C-Mo/C catalysts are essentially the same, only the particle size and/or ordering differs. In Co/C catalysts at low sulfidation temps. a highly dispersed Co-sulfide species is formed that by MES cannot be distinguished from Co in the \"Co-Mo-S\" phase. Upon sulfidation at higher temps. the 'Co-sulfide' species sinter and after sulfidation up to 673 Deg K highly dispersed Co9S8-like phases are formed. [on SciFinder (R)]
Original languageEnglish
Pages (from-to)538-547
Number of pages10
JournalPreprints - American Chemical Society, Division of Petroleum Chemistry
Volume39
Issue number4
Publication statusPublished - 1994

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