Numerical simulations of the impact of tree planting on airflow and traffic pollutant dispersion in urban street canyons have been performed using the commercial CFD (Computational Fluid Dynamics) code MISKAM. A k-e turbulence model including additional terms for the treatment of vegetation, has been employed to close the Reynolds-averaged-Navier-Stokes (RANS) equations. The numerical results were compared to wind tunnel data. In the case of the investigated wind direction perpendicular to the street axis, the presence of trees lead to increased pollutant concentrations inside the canyon. Concentrations increased strongly on the upstream side of the canyon, while on the downstream side a small concentration decrease could be observed. Lower flow velocities and higher pollutant concentrations were found in the numerical simulations when directly compared to the experimental results. However, the impact of tree planting on airflow and concentration fields when compared to the treeless street canyon as a reference configuration were simulated quite well, meaning that relative changes were similar in the wind tunnel investigations and numerical computations. This feature qualifies MISKAM for use as a tool for assessing the impacts of vegetation on local air quality.