Abstract
Recent experiments on polyelectrolyte membranes have clearly shown that at operating temperatures perfluoroimide acid (PFIA) has a higher electrical conductivity than widely used Nafion. In the present paper classical molecular-dynamics simulations were carried out to study the structural properties of both materials, and the proton and water transport in the corresponding membranes at T=300 K and T=353 K. In this temperature range, the temperature effects on the hydrated internal polyelectrolyte structure were found to be negligible. The PFIA has longer side chains across a wide range of hydration levels which would have promoted more trapping of water and hydronium ions in PFIA. Indeed, the average number of water molecules in the first hydration shell around the side-chain protogenic groups was found to be higher in PFIA than in Nafion. Our simulations showed the formation of large continuous water clusters and connected pore volumes in PFIA at high hydration levels which promotes conductivity. The diffusivity constants for hydronium ions and water increase with increasing hydration and increasing temperature. Unlike the experimental conductivities, the simulated data for PFIA were comparable to those of Nafion at high hydration levels. Note that the experimentally measured conductivity in PFIA is both due to vehicular transport of ions, which can be resolved using classical molecular dynamics, and structural Grotthuss diffusion, which cannot be resolved in our simulations. Interestingly, we observed a higher total number of water molecules in the first coordination shell around hydronium in PFIA than in Nafion at higher hydration levels. This should aid in more hydrogen bonding between hydronium and water in PFIA which, in turn, should help in structural diffusion. Finally, we discuss our preliminary results and some peculiarities of the proton transport in Nafion membranes filled with the graphene oxide nanoflakes.
| Language | English |
|---|---|
| Title of host publication | 9th International Conference on Times of Polymers and Composites |
| Subtitle of host publication | From Aerospace to Nanotechnology |
| Publisher | American Institute of Physics |
| Number of pages | 4 |
| ISBN (Electronic) | 9780735416970 |
| DOIs | |
| State | Published - 11 Jul 2018 |
| Event | 9th International Conference on Times of Polymers and Composites: From Aerospace to Nanotechnology - Ischia, Naples, Italy Duration: 17 Jun 2018 → 21 Jun 2018 |
Publication series
| Name | AIP Conference Proceedings |
|---|---|
| No. | 1 |
| Volume | 1981 |
| ISSN (Print) | 0094-243X |
Conference
| Conference | 9th International Conference on Times of Polymers and Composites: From Aerospace to Nanotechnology |
|---|---|
| Country | Italy |
| City | Ischia, Naples |
| Period | 17/06/18 → 21/06/18 |
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Keywords
- flow battery
- hydronium diffusion
- molecular dynamics
- nanocomposite
- polyelectrolyte membrane
Cite this
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Novel polyelectrolyte membranes for fuel and flow batteries : insights from simulations. / Sengupta, Soumyadipta; Kritikos, Giorgos; Karatasos, Konstantinos; Venkatnathan, Arun; Pant, Rakesh; Komarov, Pavel; Lyulin, Alexey V.
9th International Conference on Times of Polymers and Composites: From Aerospace to Nanotechnology. American Institute of Physics, 2018. 020004 (AIP Conference Proceedings; Vol. 1981, No. 1).Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › Academic › peer-review
TY - GEN
T1 - Novel polyelectrolyte membranes for fuel and flow batteries
T2 - insights from simulations
AU - Sengupta,Soumyadipta
AU - Kritikos,Giorgos
AU - Karatasos,Konstantinos
AU - Venkatnathan,Arun
AU - Pant,Rakesh
AU - Komarov,Pavel
AU - Lyulin,Alexey V.
PY - 2018/7/11
Y1 - 2018/7/11
N2 - Recent experiments on polyelectrolyte membranes have clearly shown that at operating temperatures perfluoroimide acid (PFIA) has a higher electrical conductivity than widely used Nafion. In the present paper classical molecular-dynamics simulations were carried out to study the structural properties of both materials, and the proton and water transport in the corresponding membranes at T=300 K and T=353 K. In this temperature range, the temperature effects on the hydrated internal polyelectrolyte structure were found to be negligible. The PFIA has longer side chains across a wide range of hydration levels which would have promoted more trapping of water and hydronium ions in PFIA. Indeed, the average number of water molecules in the first hydration shell around the side-chain protogenic groups was found to be higher in PFIA than in Nafion. Our simulations showed the formation of large continuous water clusters and connected pore volumes in PFIA at high hydration levels which promotes conductivity. The diffusivity constants for hydronium ions and water increase with increasing hydration and increasing temperature. Unlike the experimental conductivities, the simulated data for PFIA were comparable to those of Nafion at high hydration levels. Note that the experimentally measured conductivity in PFIA is both due to vehicular transport of ions, which can be resolved using classical molecular dynamics, and structural Grotthuss diffusion, which cannot be resolved in our simulations. Interestingly, we observed a higher total number of water molecules in the first coordination shell around hydronium in PFIA than in Nafion at higher hydration levels. This should aid in more hydrogen bonding between hydronium and water in PFIA which, in turn, should help in structural diffusion. Finally, we discuss our preliminary results and some peculiarities of the proton transport in Nafion membranes filled with the graphene oxide nanoflakes.
AB - Recent experiments on polyelectrolyte membranes have clearly shown that at operating temperatures perfluoroimide acid (PFIA) has a higher electrical conductivity than widely used Nafion. In the present paper classical molecular-dynamics simulations were carried out to study the structural properties of both materials, and the proton and water transport in the corresponding membranes at T=300 K and T=353 K. In this temperature range, the temperature effects on the hydrated internal polyelectrolyte structure were found to be negligible. The PFIA has longer side chains across a wide range of hydration levels which would have promoted more trapping of water and hydronium ions in PFIA. Indeed, the average number of water molecules in the first hydration shell around the side-chain protogenic groups was found to be higher in PFIA than in Nafion. Our simulations showed the formation of large continuous water clusters and connected pore volumes in PFIA at high hydration levels which promotes conductivity. The diffusivity constants for hydronium ions and water increase with increasing hydration and increasing temperature. Unlike the experimental conductivities, the simulated data for PFIA were comparable to those of Nafion at high hydration levels. Note that the experimentally measured conductivity in PFIA is both due to vehicular transport of ions, which can be resolved using classical molecular dynamics, and structural Grotthuss diffusion, which cannot be resolved in our simulations. Interestingly, we observed a higher total number of water molecules in the first coordination shell around hydronium in PFIA than in Nafion at higher hydration levels. This should aid in more hydrogen bonding between hydronium and water in PFIA which, in turn, should help in structural diffusion. Finally, we discuss our preliminary results and some peculiarities of the proton transport in Nafion membranes filled with the graphene oxide nanoflakes.
KW - flow battery
KW - hydronium diffusion
KW - molecular dynamics
KW - nanocomposite
KW - polyelectrolyte membrane
UR - http://www.scopus.com/inward/record.url?scp=85049942505&partnerID=8YFLogxK
U2 - 10.1063/1.5045866
DO - 10.1063/1.5045866
M3 - Conference contribution
T3 - AIP Conference Proceedings
BT - 9th International Conference on Times of Polymers and Composites
PB - American Institute of Physics
ER -