Novel glycopolymer brushes via ATRP : 1. Synthesis and characterization

R. Fleet, E. van den Dungen, L. Klumperman

Research output: Contribution to journalArticleAcademicpeer-review

7 Citations (Scopus)

Abstract

The synthesis and characterization of a series of glycopolymer brushes with P(methyl 6-O-methacryloyl-a-D-glucoside) (P(6-O-MMAGIc)) side chains (SCs) is reported. The formation of well-defined glycopolymer brushes is confirmed by 1H NMR spectroscopy and size exclusion chromatography (SEC) with a MALLS detector. Four multifunctional macroinitiators with different topologies and molar masses are prepared. The P(6-O-MMAGIc) SCs are cleaved from the backbone and analyzed by 1H NMR and SEC–MALLS, which further confirmed the synthesis of well-defined glycopolymer brushes. The grafting efficiency of P(6-O-MMAGIc) from the different macroinitiators are determined to be in the range 0.37 <f <0.55.
Original languageEnglish
Pages (from-to)2191-2208
JournalMacromolecular Chemistry and Physics
Volume212
DOIs
Publication statusPublished - 2011

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