Nonoxidative Dehydroaromatization of Methane

Nikolay Kosinov; Emiel J.M. Hensen

doi:10.1002/9783527699827.ch20

Nonoxidative Dehydroaromatization of Methane

Research output: Chapter in Book/Report/Conference proceeding › Chapter › Academic › peer-review

Abstract

In this chapter, the basics of the technology for the conversion of methane to aromatics and hydrogen by Mo/HZSM-5 catalysts are discussed. After introducing the main thermodynamic considerations of nonoxidative methane conversion, we highlight the physicochemical properties of the catalysts used in this process, the reaction mechanism, and the deactivation by coke deposition that limits commercialization of this reaction. Recent developments in improving catalyst stability (hierarchization, periodic reaction-regeneration operation, and novel reactor designs) are briefly reviewed.

Original language	English
Title of host publication	Nanotechnology in Catalysis
Subtitle of host publication	Applications in the Chemical Industry, Energy Development, and Environment Protection
Editors	Marcel Van de Voorde, Bert Sels
Publisher	Wiley-Liss Inc.
Chapter	20
Pages	469-481
Number of pages	13
ISBN (Electronic)	9783527699827
ISBN (Print)	9783527339143
DOIs	https://doi.org/10.1002/9783527699827.ch20
Publication status	Published - 23 Jun 2017

Bibliographical note

Publisher Copyright:
© 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Boschstr. 12, 69469 Weinheim, Germany.

Keywords

catalysis
methane aromatization
natural gas valorization
zeolites

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10.1002/9783527699827.ch20

Cite this

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doi = "10.1002/9783527699827.ch20",

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Nonoxidative Dehydroaromatization of Methane. / Kosinov, Nikolay ; Hensen, Emiel J.M.
Nanotechnology in Catalysis: Applications in the Chemical Industry, Energy Development, and Environment Protection. ed. / Marcel Van de Voorde; Bert Sels. Wiley-Liss Inc., 2017. p. 469-481.

Research output: Chapter in Book/Report/Conference proceeding › Chapter › Academic › peer-review

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T1 - Nonoxidative Dehydroaromatization of Methane

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AU - Hensen, Emiel J.M.

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N2 - In this chapter, the basics of the technology for the conversion of methane to aromatics and hydrogen by Mo/HZSM-5 catalysts are discussed. After introducing the main thermodynamic considerations of nonoxidative methane conversion, we highlight the physicochemical properties of the catalysts used in this process, the reaction mechanism, and the deactivation by coke deposition that limits commercialization of this reaction. Recent developments in improving catalyst stability (hierarchization, periodic reaction-regeneration operation, and novel reactor designs) are briefly reviewed.

AB - In this chapter, the basics of the technology for the conversion of methane to aromatics and hydrogen by Mo/HZSM-5 catalysts are discussed. After introducing the main thermodynamic considerations of nonoxidative methane conversion, we highlight the physicochemical properties of the catalysts used in this process, the reaction mechanism, and the deactivation by coke deposition that limits commercialization of this reaction. Recent developments in improving catalyst stability (hierarchization, periodic reaction-regeneration operation, and novel reactor designs) are briefly reviewed.

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KW - methane aromatization

KW - natural gas valorization

KW - zeolites

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A2 - Van de Voorde, Marcel

A2 - Sels, Bert

PB - Wiley-Liss Inc.

ER -

Nonoxidative Dehydroaromatization of Methane

Abstract

Bibliographical note

Keywords

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