NMR spectra of some cyclic dienyl anions

H. Kloosterziel; J.A.A. Drunen, van

doi:10.1002/recl.19700890404

NMR spectra of some cyclic dienyl anions

H. Kloosterziel
, J.A.A. Drunen, van

Chemical Engineering and Chemistry

Research output: Contribution to journal › Article › Academic › peer-review

36 Citations (Scopus)

Abstract

The NMR spectra of the cyclohexadienyl anion and of the cyclooctadienyl anion (I) were studied. The strongly bent anion I shows at low temps. reversible line broadening. At higher temps. I electrocyclizes to the bicyclo[3.3.0]octenyl anion. In neither of these anions there is substantial 1,5 overlap (homoaromaticity). [on SciFinder (R)]

Original language	English
Pages (from-to)	368-374
Journal	Recueil des Travaux Chimiques des Pays-Bas
Volume	89
Issue number	4
DOIs	https://doi.org/10.1002/recl.19700890404
Publication status	Published - 1970

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title = "NMR spectra of some cyclic dienyl anions",

abstract = "The NMR spectra of the cyclohexadienyl anion and of the cyclooctadienyl anion (I) were studied. The strongly bent anion I shows at low temps. reversible line broadening. At higher temps. I electrocyclizes to the bicyclo[3.3.0]octenyl anion. In neither of these anions there is substantial 1,5 overlap (homoaromaticity). [on SciFinder (R)]",

author = "H. Kloosterziel and \{Drunen, van\}, J.A.A.",

year = "1970",

doi = "10.1002/recl.19700890404",

language = "English",

volume = "89",

pages = "368--374",

journal = "Recueil des Travaux Chimiques des Pays-Bas",

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publisher = "Royal Netherlands Chemical Society",

number = "4",

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T1 - NMR spectra of some cyclic dienyl anions

AU - Kloosterziel, H.

AU - Drunen, van, J.A.A.

PY - 1970

Y1 - 1970

N2 - The NMR spectra of the cyclohexadienyl anion and of the cyclooctadienyl anion (I) were studied. The strongly bent anion I shows at low temps. reversible line broadening. At higher temps. I electrocyclizes to the bicyclo[3.3.0]octenyl anion. In neither of these anions there is substantial 1,5 overlap (homoaromaticity). [on SciFinder (R)]

AB - The NMR spectra of the cyclohexadienyl anion and of the cyclooctadienyl anion (I) were studied. The strongly bent anion I shows at low temps. reversible line broadening. At higher temps. I electrocyclizes to the bicyclo[3.3.0]octenyl anion. In neither of these anions there is substantial 1,5 overlap (homoaromaticity). [on SciFinder (R)]

U2 - 10.1002/recl.19700890404

DO - 10.1002/recl.19700890404

M3 - Article

SN - 0165-0513

VL - 89

SP - 368

EP - 374

JO - Recueil des Travaux Chimiques des Pays-Bas

JF - Recueil des Travaux Chimiques des Pays-Bas

IS - 4

ER -

NMR spectra of some cyclic dienyl anions

Abstract

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