NMR spectra and configuration of phenylallyl and related anions

G.J. Heiszwolf; H. Kloosterziel

doi:10.1002/recl.19670861211

NMR spectra and configuration of phenylallyl and related anions

G.J. Heiszwolf, H. Kloosterziel

Department of Chemical Engineering and Chemistry

Research output: Contribution to journal › Article › Academic › peer-review

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Abstract

A number of phenyl-substituted allyl anions and corresponding isoelectronic oxaallyl anions have been obtained by reacting phenyl-substituted propenes, phenylacetaldehyde and benzyl methyl ketone with potassium amide in liquid ammonia. The NMR spectra of the anions are decribed. They yield information on the distribution of the negative charge and on the configurations. The configurational stability is also discussed.

Original language	English
Pages (from-to)	1345-1355
Number of pages	5
Journal	Recueil des Travaux Chimiques des Pays-Bas
Volume	86
Issue number	12
DOIs	https://doi.org/10.1002/recl.19670861211
Publication status	Published - 1967

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title = "NMR spectra and configuration of phenylallyl and related anions",

abstract = "A number of phenyl-substituted allyl anions and corresponding isoelectronic oxaallyl anions have been obtained by reacting phenyl-substituted propenes, phenylacetaldehyde and benzyl methyl ketone with potassium amide in liquid ammonia. The NMR spectra of the anions are decribed. They yield information on the distribution of the negative charge and on the configurations. The configurational stability is also discussed.",

author = "G.J. Heiszwolf and H. Kloosterziel",

year = "1967",

doi = "10.1002/recl.19670861211",

language = "English",

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pages = "1345--1355",

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publisher = "Royal Netherlands Chemical Society",

number = "12",

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T1 - NMR spectra and configuration of phenylallyl and related anions

AU - Heiszwolf, G.J.

AU - Kloosterziel, H.

PY - 1967

Y1 - 1967

N2 - A number of phenyl-substituted allyl anions and corresponding isoelectronic oxaallyl anions have been obtained by reacting phenyl-substituted propenes, phenylacetaldehyde and benzyl methyl ketone with potassium amide in liquid ammonia. The NMR spectra of the anions are decribed. They yield information on the distribution of the negative charge and on the configurations. The configurational stability is also discussed.

AB - A number of phenyl-substituted allyl anions and corresponding isoelectronic oxaallyl anions have been obtained by reacting phenyl-substituted propenes, phenylacetaldehyde and benzyl methyl ketone with potassium amide in liquid ammonia. The NMR spectra of the anions are decribed. They yield information on the distribution of the negative charge and on the configurations. The configurational stability is also discussed.

U2 - 10.1002/recl.19670861211

DO - 10.1002/recl.19670861211

M3 - Article

VL - 86

SP - 1345

EP - 1355

JO - Recueil des Travaux Chimiques des Pays-Bas

JF - Recueil des Travaux Chimiques des Pays-Bas

SN - 0165-0513

IS - 12

ER -