Abstract
| Original language | English |
|---|---|
| Pages (from-to) | 8-11 |
| Journal | Recueil des Travaux Chimiques des Pays-Bas |
| Volume | 98 |
| Issue number | 1 |
| DOIs | |
| Publication status | Published - 1979 |
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Nitrogen fixation by reduced transition metal complexes : II. the influence of lithium and naphthalene as reducing species on vanadium trichloride. / Beelen, T.P.M.; Rummens, C.P.J.
In: Recueil des Travaux Chimiques des Pays-Bas, Vol. 98, No. 1, 1979, p. 8-11.Research output: Contribution to journal › Article › Academic › peer-review
TY - JOUR
T1 - Nitrogen fixation by reduced transition metal complexes : II. the influence of lithium and naphthalene as reducing species on vanadium trichloride
AU - Beelen, T.P.M.
AU - Rummens, C.P.J.
PY - 1979
Y1 - 1979
N2 - VCl3 is able to bind dinitrogen at room temperature and a N2 pressure of 1 atmosphere after reduction with Li+Np- (Np = naphthalene) or with Li + Li+Np2-. In the latter case also a direct reaction of N2 with Li + Li2+Np2- occurs, so that there are two independent nitrogen fixation reactions effective in the system VCl3 + Li + Li2+Np2-. The role of Np2- ions in this system has been investigated and a proposal for the mechanism of the reaction of Li + Li2+Np2- with N2 is made.
AB - VCl3 is able to bind dinitrogen at room temperature and a N2 pressure of 1 atmosphere after reduction with Li+Np- (Np = naphthalene) or with Li + Li+Np2-. In the latter case also a direct reaction of N2 with Li + Li2+Np2- occurs, so that there are two independent nitrogen fixation reactions effective in the system VCl3 + Li + Li2+Np2-. The role of Np2- ions in this system has been investigated and a proposal for the mechanism of the reaction of Li + Li2+Np2- with N2 is made.
U2 - 10.1002/recl.19790980105
DO - 10.1002/recl.19790980105
M3 - Article
VL - 98
SP - 8
EP - 11
JO - Recueil des Travaux Chimiques des Pays-Bas
JF - Recueil des Travaux Chimiques des Pays-Bas
SN - 0165-0513
IS - 1
ER -