Nickel-Catalyzed Isomerization of 2-Methyl-3-butenenitrile

J.B.M. Wilting; C. Müller; A.C. Hewat; D.D. Ellis; D.M. Tooke; A.L. Spek; D. Vogt

doi:10.1021/om049206p

Nickel-Catalyzed Isomerization of 2-Methyl-3-butenenitrile

J.B.M. Wilting, C. Müller, A.C. Hewat, D.D. Ellis, D.M. Tooke, A.L. Spek, D. Vogt

Inorganic Materials & Catalysis

Research output: Contribution to journal › Article › Academic › peer-review

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Abstract

The isomerization of the branched 2M3BN to the linear 3PN by a DPEphosNi species has been investigated by means of variable-temperature NMR spectroscopy, and activation parameters have been determined. An intermediate in this reaction, which is formed via C-C bond activation, could be trapped by addition of ZnCl2, and the molecular structure of the corresponding Ni(II) complex has been determined by X-ray crystallography.

Original language	English
Pages (from-to)	13-15
Journal	Organometallics
Volume	24
Issue number	1
DOIs	https://doi.org/10.1021/om049206p
Publication status	Published - 2005

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title = "Nickel-Catalyzed Isomerization of 2-Methyl-3-butenenitrile",

abstract = "The isomerization of the branched 2M3BN to the linear 3PN by a DPEphosNi species has been investigated by means of variable-temperature NMR spectroscopy, and activation parameters have been determined. An intermediate in this reaction, which is formed via C-C bond activation, could be trapped by addition of ZnCl2, and the molecular structure of the corresponding Ni(II) complex has been determined by X-ray crystallography.",

author = "J.B.M. Wilting and C. M{\"u}ller and A.C. Hewat and D.D. Ellis and D.M. Tooke and A.L. Spek and D. Vogt",

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T1 - Nickel-Catalyzed Isomerization of 2-Methyl-3-butenenitrile

AU - Wilting, J.B.M.

AU - Müller, C.

AU - Hewat, A.C.

AU - Ellis, D.D.

AU - Tooke, D.M.

AU - Spek, A.L.

AU - Vogt, D.

PY - 2005

Y1 - 2005

N2 - The isomerization of the branched 2M3BN to the linear 3PN by a DPEphosNi species has been investigated by means of variable-temperature NMR spectroscopy, and activation parameters have been determined. An intermediate in this reaction, which is formed via C-C bond activation, could be trapped by addition of ZnCl2, and the molecular structure of the corresponding Ni(II) complex has been determined by X-ray crystallography.

AB - The isomerization of the branched 2M3BN to the linear 3PN by a DPEphosNi species has been investigated by means of variable-temperature NMR spectroscopy, and activation parameters have been determined. An intermediate in this reaction, which is formed via C-C bond activation, could be trapped by addition of ZnCl2, and the molecular structure of the corresponding Ni(II) complex has been determined by X-ray crystallography.

U2 - 10.1021/om049206p

DO - 10.1021/om049206p

M3 - Article

SN - 0276-7333

VL - 24

SP - 13

EP - 15

JO - Organometallics

JF - Organometallics

IS - 1

ER -

Nickel-Catalyzed Isomerization of 2-Methyl-3-butenenitrile

Abstract

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