New Ti-Ni dense membranes with low palladium content

G.F. Tereschenko; M.M. Ermilova; V.P. Mordovin; N.V. Orekhova; V.M. Gryaznov; A. Iulianelli; F. Gallucci; A. Basile

doi:10.1016/j.ijhydene.2007.03.044

New Ti-Ni dense membranes with low palladium content

G.F. Tereschenko
, M.M. Ermilova
, V.P. Mordovin
, N.V. Orekhova
, V.M. Gryaznov
, A. Iulianelli
, F. Gallucci
, A. Basile

Research output: Contribution to journal › Article › Academic › peer-review

31 Citations (Scopus)

Abstract

The method of preparation of thin foil Ti-Ni-Pd alloy membranes with 2, 5 and 9 wt% of Pd was developed and the phase content and hydrogen permeability of membranes were studied. It was found that Pd adding into Ti-Ni alloy increases the hydrogen permeability of the foils. Thus, the permeability of the foil with 9% of Pd was about one order of magnitude higher than that of the Ti-Ni foil. Cyclohexane dehydrogenation on Pt - Re / Al2 O3 commercial catalyst carried out in a flow reactor with a Ti-Ni-Pd membrane shows the higher conversions than those of a reactor without membrane due to the hydrogen permeability through the membrane. © 2007 International Association for Hydrogen Energy. 10.1016/j.ijhydene.2007.03.044

Original language	English
Pages (from-to)	4016-4022
Number of pages	7
Journal	International Journal of Hydrogen Energy
Volume	32
Issue number	16
DOIs	https://doi.org/10.1016/j.ijhydene.2007.03.044
Publication status	Published - 2007

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title = "New Ti-Ni dense membranes with low palladium content",

abstract = "The method of preparation of thin foil Ti-Ni-Pd alloy membranes with 2, 5 and 9 wt\% of Pd was developed and the phase content and hydrogen permeability of membranes were studied. It was found that Pd adding into Ti-Ni alloy increases the hydrogen permeability of the foils. Thus, the permeability of the foil with 9\% of Pd was about one order of magnitude higher than that of the Ti-Ni foil. Cyclohexane dehydrogenation on Pt - Re / Al2 O3 commercial catalyst carried out in a flow reactor with a Ti-Ni-Pd membrane shows the higher conversions than those of a reactor without membrane due to the hydrogen permeability through the membrane. {\textcopyright} 2007 International Association for Hydrogen Energy. 10.1016/j.ijhydene.2007.03.044",

author = "G.F. Tereschenko and M.M. Ermilova and V.P. Mordovin and N.V. Orekhova and V.M. Gryaznov and A. Iulianelli and F. Gallucci and A. Basile",

year = "2007",

doi = "10.1016/j.ijhydene.2007.03.044",

language = "English",

volume = "32",

pages = "4016--4022",

journal = "International Journal of Hydrogen Energy",

issn = "0360-3199",

publisher = "Elsevier",

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}

TY - JOUR

T1 - New Ti-Ni dense membranes with low palladium content

AU - Tereschenko, G.F.

AU - Ermilova, M.M.

AU - Mordovin, V.P.

AU - Orekhova, N.V.

AU - Gryaznov, V.M.

AU - Iulianelli, A.

AU - Gallucci, F.

AU - Basile, A.

PY - 2007

Y1 - 2007

N2 - The method of preparation of thin foil Ti-Ni-Pd alloy membranes with 2, 5 and 9 wt% of Pd was developed and the phase content and hydrogen permeability of membranes were studied. It was found that Pd adding into Ti-Ni alloy increases the hydrogen permeability of the foils. Thus, the permeability of the foil with 9% of Pd was about one order of magnitude higher than that of the Ti-Ni foil. Cyclohexane dehydrogenation on Pt - Re / Al2 O3 commercial catalyst carried out in a flow reactor with a Ti-Ni-Pd membrane shows the higher conversions than those of a reactor without membrane due to the hydrogen permeability through the membrane. © 2007 International Association for Hydrogen Energy. 10.1016/j.ijhydene.2007.03.044

AB - The method of preparation of thin foil Ti-Ni-Pd alloy membranes with 2, 5 and 9 wt% of Pd was developed and the phase content and hydrogen permeability of membranes were studied. It was found that Pd adding into Ti-Ni alloy increases the hydrogen permeability of the foils. Thus, the permeability of the foil with 9% of Pd was about one order of magnitude higher than that of the Ti-Ni foil. Cyclohexane dehydrogenation on Pt - Re / Al2 O3 commercial catalyst carried out in a flow reactor with a Ti-Ni-Pd membrane shows the higher conversions than those of a reactor without membrane due to the hydrogen permeability through the membrane. © 2007 International Association for Hydrogen Energy. 10.1016/j.ijhydene.2007.03.044

U2 - 10.1016/j.ijhydene.2007.03.044

DO - 10.1016/j.ijhydene.2007.03.044

M3 - Article

SN - 0360-3199

VL - 32

SP - 4016

EP - 4022

JO - International Journal of Hydrogen Energy

JF - International Journal of Hydrogen Energy

IS - 16

ER -

New Ti-Ni dense membranes with low palladium content

Abstract

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