New soluble functional polymers by free-radical copolymerization of methacrylates and bipyridine ruthenium complexes

E. Holder, M.A.R. Meier, V.N. Marin, U.S. Schubert

Research output: Contribution to journalArticleAcademicpeer-review

35 Citations (Scopus)
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Abstract

The luminescent complex [4-(3-hydroxypropyl)-4-methyl-2,2-bipyridine]-bis(2,2-bipyridine)-ruthenium(II)-bis(hexafluoroantimonate) and its methacrylate derivative were successfully synthesized and fully characterized by two-dimensional 1H and 13C{1H} NMR techniques [correlation spectroscopy (COSY) and heteronuclear multiple-quantum coherence experiment (HMQC)], as well as matrix-assisted laser desorption ionization time-of-flight mass spectrometry. The respective labeled methyl methacrylate-ruthenium(polypyridyl) copolymers were obtained by free-radical copolymerization with methyl methacrylate and were characterized utilizing NMR, IR, and UV-visible spectroscopy and gel permeation chromatography.
Original languageEnglish
Pages (from-to)3954-3964
JournalJournal of Polymer Science, Part A: Polymer Chemistry
Volume41
Issue number24
DOIs
Publication statusPublished - 2003

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