New aspects on the cohesion of simple compounds. V

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Abstract

The Debye and Keesom contributions to the boiling points of methane, ethane, propane and ethene derivatives are studied, and several remarkable numerical relationships between them are found. These relationships can be explained theoretically. Moreover, they permit the calculation of the Debye and Keesom contributions to the boiling points of the propane derivatives, which hitherto could not be estimated empirically. A method is developed, according to which it is possible to calculate theoretically the values k in the formulae for the London contribution to the boiling points of the methane, ethane and propane derivatives. The agreement with the empirical values is satisfactory. Some minor questions, left open for further discussion in earlier papers, are treated.

Original languageEnglish
Pages (from-to)771-781
Number of pages11
JournalRecueil des Travaux Chimiques des Pays‐Bas
Volume61
Issue number11
DOIs
Publication statusPublished - 1942

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Propane
Boiling point
Ethane
Methane
Derivatives

Cite this

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title = "New aspects on the cohesion of simple compounds. V",
abstract = "The Debye and Keesom contributions to the boiling points of methane, ethane, propane and ethene derivatives are studied, and several remarkable numerical relationships between them are found. These relationships can be explained theoretically. Moreover, they permit the calculation of the Debye and Keesom contributions to the boiling points of the propane derivatives, which hitherto could not be estimated empirically. A method is developed, according to which it is possible to calculate theoretically the values k in the formulae for the London contribution to the boiling points of the methane, ethane and propane derivatives. The agreement with the empirical values is satisfactory. Some minor questions, left open for further discussion in earlier papers, are treated.",
author = "Stevels, {J. M.}",
year = "1942",
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journal = "Recueil des Travaux Chimiques des Pays-Bas",
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}

New aspects on the cohesion of simple compounds. V. / Stevels, J. M.

In: Recueil des Travaux Chimiques des Pays‐Bas, Vol. 61, No. 11, 1942, p. 771-781.

Research output: Contribution to journalArticleAcademicpeer-review

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