Network density and diene conversion in peroxide-cured gumstock EPDM rubbers : a solid-state NMR study

R.A. Orza, P.C.M.M. Magusin, V.M. Litvinov, M. Duin, van, M.A.J. Michels

Research output: Chapter in Book/Report/Conference proceedingConference contributionAcademicpeer-review

20 Citations (Scopus)

Abstract

Peroxide-cross-linked EPM and EPDM rubbers have been investigated with magic-angle spinning 1H NMR spectroscopy and static 1H NMR relaxometry. The results yield a consistent nanoscale picture of the chemical and physical network properties in terms of chemical cross-links formed via macro-radical combination, chemical cross-links formed via addition to the double bonds, and physical cross-links resulting from chain entanglements.
Original languageEnglish
Title of host publicationPolymer spectroscopy : selected contributions from the 16th European Symposium on Polymer Spectroscopy (ESOPS 16), Kerkrade, The Netherlands
EditorsJ.G.P. Goossens, J.A.J. Jansen
Place of PublicationWeinheim
PublisherWiley-VCH Verlag
Pages144-148
DOIs
Publication statusPublished - 2005
Eventconference; ESOPS 16 : European Symposium on Polymer Spectroscopy ; 16 (Kerkrade) : 2005.05.29-06.01; 2005-05-29; 2005-06-01 -
Duration: 29 May 20051 Jun 2005

Publication series

NameMacromolecular Symposia
Volume230
ISSN (Print)1022-1360

Conference

Conferenceconference; ESOPS 16 : European Symposium on Polymer Spectroscopy ; 16 (Kerkrade) : 2005.05.29-06.01; 2005-05-29; 2005-06-01
Period29/05/051/06/05
OtherESOPS 16 : European Symposium on Polymer Spectroscopy ; 16 (Kerkrade) : 2005.05.29-06.01

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