Network density and diene conversion in peroxide-cured gumstock EPDM rubbers : a solid-state NMR study

R.A. Orza, P.C.M.M. Magusin, V.M. Litvinov, M. Duin, van, M.A.J. Michels

Research output: Chapter in Book/Report/Conference proceedingConference contributionAcademicpeer-review

18 Citations (Scopus)

Abstract

Peroxide-cross-linked EPM and EPDM rubbers have been investigated with magic-angle spinning 1H NMR spectroscopy and static 1H NMR relaxometry. The results yield a consistent nanoscale picture of the chemical and physical network properties in terms of chemical cross-links formed via macro-radical combination, chemical cross-links formed via addition to the double bonds, and physical cross-links resulting from chain entanglements.
Original languageEnglish
Title of host publicationPolymer spectroscopy : selected contributions from the 16th European Symposium on Polymer Spectroscopy (ESOPS 16), Kerkrade, The Netherlands
EditorsJ.G.P. Goossens, J.A.J. Jansen
Place of PublicationWeinheim
PublisherWiley-VCH Verlag
Pages144-148
DOIs
Publication statusPublished - 2005
Eventconference; ESOPS 16 : European Symposium on Polymer Spectroscopy ; 16 (Kerkrade) : 2005.05.29-06.01; 2005-05-29; 2005-06-01 -
Duration: 29 May 20051 Jun 2005

Publication series

NameMacromolecular Symposia
Volume230
ISSN (Print)1022-1360

Conference

Conferenceconference; ESOPS 16 : European Symposium on Polymer Spectroscopy ; 16 (Kerkrade) : 2005.05.29-06.01; 2005-05-29; 2005-06-01
Period29/05/051/06/05
OtherESOPS 16 : European Symposium on Polymer Spectroscopy ; 16 (Kerkrade) : 2005.05.29-06.01

Fingerprint

Rubber
Peroxides
Nuclear magnetic resonance
Magic angle spinning
Nuclear magnetic resonance spectroscopy
Macros

Cite this

Orza, R. A., Magusin, P. C. M. M., Litvinov, V. M., Duin, van, M., & Michels, M. A. J. (2005). Network density and diene conversion in peroxide-cured gumstock EPDM rubbers : a solid-state NMR study. In J. G. P. Goossens, & J. A. J. Jansen (Eds.), Polymer spectroscopy : selected contributions from the 16th European Symposium on Polymer Spectroscopy (ESOPS 16), Kerkrade, The Netherlands (pp. 144-148). (Macromolecular Symposia; Vol. 230). Weinheim: Wiley-VCH Verlag. https://doi.org/10.1002/masy.200551153
Orza, R.A. ; Magusin, P.C.M.M. ; Litvinov, V.M. ; Duin, van, M. ; Michels, M.A.J. / Network density and diene conversion in peroxide-cured gumstock EPDM rubbers : a solid-state NMR study. Polymer spectroscopy : selected contributions from the 16th European Symposium on Polymer Spectroscopy (ESOPS 16), Kerkrade, The Netherlands. editor / J.G.P. Goossens ; J.A.J. Jansen. Weinheim : Wiley-VCH Verlag, 2005. pp. 144-148 (Macromolecular Symposia).
@inproceedings{8061cb06b7bb4c36811b591e1a3588d6,
title = "Network density and diene conversion in peroxide-cured gumstock EPDM rubbers : a solid-state NMR study",
abstract = "Peroxide-cross-linked EPM and EPDM rubbers have been investigated with magic-angle spinning 1H NMR spectroscopy and static 1H NMR relaxometry. The results yield a consistent nanoscale picture of the chemical and physical network properties in terms of chemical cross-links formed via macro-radical combination, chemical cross-links formed via addition to the double bonds, and physical cross-links resulting from chain entanglements.",
author = "R.A. Orza and P.C.M.M. Magusin and V.M. Litvinov and {Duin, van}, M. and M.A.J. Michels",
year = "2005",
doi = "10.1002/masy.200551153",
language = "English",
series = "Macromolecular Symposia",
publisher = "Wiley-VCH Verlag",
pages = "144--148",
editor = "J.G.P. Goossens and J.A.J. Jansen",
booktitle = "Polymer spectroscopy : selected contributions from the 16th European Symposium on Polymer Spectroscopy (ESOPS 16), Kerkrade, The Netherlands",
address = "Germany",

}

Orza, RA, Magusin, PCMM, Litvinov, VM, Duin, van, M & Michels, MAJ 2005, Network density and diene conversion in peroxide-cured gumstock EPDM rubbers : a solid-state NMR study. in JGP Goossens & JAJ Jansen (eds), Polymer spectroscopy : selected contributions from the 16th European Symposium on Polymer Spectroscopy (ESOPS 16), Kerkrade, The Netherlands. Macromolecular Symposia, vol. 230, Wiley-VCH Verlag, Weinheim, pp. 144-148, conference; ESOPS 16 : European Symposium on Polymer Spectroscopy ; 16 (Kerkrade) : 2005.05.29-06.01; 2005-05-29; 2005-06-01, 29/05/05. https://doi.org/10.1002/masy.200551153

Network density and diene conversion in peroxide-cured gumstock EPDM rubbers : a solid-state NMR study. / Orza, R.A.; Magusin, P.C.M.M.; Litvinov, V.M.; Duin, van, M.; Michels, M.A.J.

Polymer spectroscopy : selected contributions from the 16th European Symposium on Polymer Spectroscopy (ESOPS 16), Kerkrade, The Netherlands. ed. / J.G.P. Goossens; J.A.J. Jansen. Weinheim : Wiley-VCH Verlag, 2005. p. 144-148 (Macromolecular Symposia; Vol. 230).

Research output: Chapter in Book/Report/Conference proceedingConference contributionAcademicpeer-review

TY - GEN

T1 - Network density and diene conversion in peroxide-cured gumstock EPDM rubbers : a solid-state NMR study

AU - Orza, R.A.

AU - Magusin, P.C.M.M.

AU - Litvinov, V.M.

AU - Duin, van, M.

AU - Michels, M.A.J.

PY - 2005

Y1 - 2005

N2 - Peroxide-cross-linked EPM and EPDM rubbers have been investigated with magic-angle spinning 1H NMR spectroscopy and static 1H NMR relaxometry. The results yield a consistent nanoscale picture of the chemical and physical network properties in terms of chemical cross-links formed via macro-radical combination, chemical cross-links formed via addition to the double bonds, and physical cross-links resulting from chain entanglements.

AB - Peroxide-cross-linked EPM and EPDM rubbers have been investigated with magic-angle spinning 1H NMR spectroscopy and static 1H NMR relaxometry. The results yield a consistent nanoscale picture of the chemical and physical network properties in terms of chemical cross-links formed via macro-radical combination, chemical cross-links formed via addition to the double bonds, and physical cross-links resulting from chain entanglements.

U2 - 10.1002/masy.200551153

DO - 10.1002/masy.200551153

M3 - Conference contribution

T3 - Macromolecular Symposia

SP - 144

EP - 148

BT - Polymer spectroscopy : selected contributions from the 16th European Symposium on Polymer Spectroscopy (ESOPS 16), Kerkrade, The Netherlands

A2 - Goossens, J.G.P.

A2 - Jansen, J.A.J.

PB - Wiley-VCH Verlag

CY - Weinheim

ER -

Orza RA, Magusin PCMM, Litvinov VM, Duin, van M, Michels MAJ. Network density and diene conversion in peroxide-cured gumstock EPDM rubbers : a solid-state NMR study. In Goossens JGP, Jansen JAJ, editors, Polymer spectroscopy : selected contributions from the 16th European Symposium on Polymer Spectroscopy (ESOPS 16), Kerkrade, The Netherlands. Weinheim: Wiley-VCH Verlag. 2005. p. 144-148. (Macromolecular Symposia). https://doi.org/10.1002/masy.200551153