Nanoporous membranes of hydrogen-bridged smectic networks with nanometer transverse pore dimensions

C.L. Gonzalez; C.W.M. Bastiaansen; Johan Lub; J. Loos; K. Lu; H.J. Wondergem; D.J. Broer

doi:10.1002/adma.200702002

Nanoporous membranes of hydrogen-bridged smectic networks with nanometer transverse pore dimensions

C.L. Gonzalez, C.W.M. Bastiaansen, Johan Lub, J. Loos, K. Lu, H.J. Wondergem, D.J. Broer

Research output: Contribution to journal › Article › Academic › peer-review

56 Citations (Scopus)

12 Downloads (Pure)

Abstract

Nanoporous membranes are made based on photoreactive hydrogen-bridged smectic liquid crystal dimers. The self-assembled layered structure is locked by photopolymerization. The hydrogen bridges are reversibly opened by heating or by changing the pH. This forms periodic pores of which the integrity is conserved by a covalent crosslinker, setting the spacing at ca. 1 nm. The pores are covered with carboxylic anions that bind to cations or to amines.

Original language	English
Pages (from-to)	1246-1252
Number of pages	7
Journal	Advanced Materials
Volume	20
Issue number	7
DOIs	https://doi.org/10.1002/adma.200702002
Publication status	Published - 2008

Access to Document

10.1002/adma.200702002

Center for Multiscale Electron Microscopy (CMEM)
Heiner Friedrich (Manager), Rick Joosten (Education/research officer), Pauline Schmit (Education/research officer), Ingeborg Schreur - Piet (Other) & Anne Spoelstra (Education/research officer)
Physical Chemistry
Facility/equipment: Research lab

Cite this

@article{6324a89f48c945739b785a3d3eb53746,

title = "Nanoporous membranes of hydrogen-bridged smectic networks with nanometer transverse pore dimensions",

abstract = "Nanoporous membranes are made based on photoreactive hydrogen-bridged smectic liquid crystal dimers. The self-assembled layered structure is locked by photopolymerization. The hydrogen bridges are reversibly opened by heating or by changing the pH. This forms periodic pores of which the integrity is conserved by a covalent crosslinker, setting the spacing at ca. 1 nm. The pores are covered with carboxylic anions that bind to cations or to amines.",

author = "C.L. Gonzalez and C.W.M. Bastiaansen and Johan Lub and J. Loos and K. Lu and H.J. Wondergem and D.J. Broer",

year = "2008",

doi = "10.1002/adma.200702002",

language = "English",

volume = "20",

pages = "1246--1252",

journal = "Advanced Materials",

issn = "0935-9648",

publisher = "Wiley-VCH Verlag",

number = "7",

}

TY - JOUR

T1 - Nanoporous membranes of hydrogen-bridged smectic networks with nanometer transverse pore dimensions

AU - Gonzalez, C.L.

AU - Bastiaansen, C.W.M.

AU - Lub, Johan

AU - Loos, J.

AU - Lu, K.

AU - Wondergem, H.J.

AU - Broer, D.J.

PY - 2008

Y1 - 2008

N2 - Nanoporous membranes are made based on photoreactive hydrogen-bridged smectic liquid crystal dimers. The self-assembled layered structure is locked by photopolymerization. The hydrogen bridges are reversibly opened by heating or by changing the pH. This forms periodic pores of which the integrity is conserved by a covalent crosslinker, setting the spacing at ca. 1 nm. The pores are covered with carboxylic anions that bind to cations or to amines.

AB - Nanoporous membranes are made based on photoreactive hydrogen-bridged smectic liquid crystal dimers. The self-assembled layered structure is locked by photopolymerization. The hydrogen bridges are reversibly opened by heating or by changing the pH. This forms periodic pores of which the integrity is conserved by a covalent crosslinker, setting the spacing at ca. 1 nm. The pores are covered with carboxylic anions that bind to cations or to amines.

U2 - 10.1002/adma.200702002

DO - 10.1002/adma.200702002

M3 - Article

SN - 0935-9648

VL - 20

SP - 1246

EP - 1252

JO - Advanced Materials

JF - Advanced Materials

IS - 7

ER -

Nanoporous membranes of hydrogen-bridged smectic networks with nanometer transverse pore dimensions

Abstract

Access to Document

Fingerprint

Equipment

Center for Multiscale Electron Microscopy (CMEM)

Cite this