Multihydroxy-functional oligophenylene oxide

H. Oevering; G.H. Werumeus Buning; E.W. Meijer; H.A.M. Aert, van; G.J. J. Out

Multihydroxy-functional oligophenylene oxide

H. Oevering (Inventor)
, G.H. Werumeus Buning (Inventor)
, E.W. Meijer (Inventor)
, H.A.M. Aert, van (Inventor)
, G.J. J. Out (Inventor)

Research output: Patent › Patent publication

Abstract

The title oligomers are obtainable by reacting a compd. contg. hydroxyaryl comprising >=3 hydroxyaryl groups 2-R2,4-R1,6-R3-C6H3OH (R1 = an arom., aliph. or cycloaliph. group contg. 1-50 C atoms, R2, R3 = H or an arom., aliph. or cycloaliph. group contg. 1-50 C atoms, or 2 of the R1, R2 or R3 groups together constitute a ring structure contg. 4-50 C atoms) with a polyphenylene oxide in the presence of a catalyst complex comprising a transition metal and amine. Hydroxy-terminal polyoxyphenylene [no.-av. mol. wt. (Mn) 8200] and tert-butylcalix(8)arene were mixed in CCl4 in the presence of CuCl2 and dimethylaminopyridine, bubbling through O:N mixt. for 40 h at room temp. to give an oligomer having Mn 11,590

Original language	English
Patent number	WO9601865 A1
Publication status	Published - 25 Jan 1996

Cite this

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title = "Multihydroxy-functional oligophenylene oxide",

abstract = "The title oligomers are obtainable by reacting a compd. contg. hydroxyaryl comprising >=3 hydroxyaryl groups 2-R2,4-R1,6-R3-C6H3OH (R1 = an arom., aliph. or cycloaliph. group contg. 1-50 C atoms, R2, R3 = H or an arom., aliph. or cycloaliph. group contg. 1-50 C atoms, or 2 of the R1, R2 or R3 groups together constitute a ring structure contg. 4-50 C atoms) with a polyphenylene oxide in the presence of a catalyst complex comprising a transition metal and amine. Hydroxy-terminal polyoxyphenylene [no.-av. mol. wt. (Mn) 8200] and tert-butylcalix(8)arene were mixed in CCl4 in the presence of CuCl2 and dimethylaminopyridine, bubbling through O:N mixt. for 40 h at room temp. to give an oligomer having Mn 11,590",

author = "H. Oevering and \{Werumeus Buning\}, G.H. and E.W. Meijer and \{Aert, van\}, H.A.M. and Out, \{G.J. J.\}",

year = "1996",

month = jan,

day = "25",

language = "English",

type = "Patent",

note = "WO9601865 A1",

}

TY - PAT

T1 - Multihydroxy-functional oligophenylene oxide

AU - Oevering, H.

AU - Werumeus Buning, G.H.

AU - Meijer, E.W.

AU - Aert, van, H.A.M.

AU - Out, G.J. J.

PY - 1996/1/25

Y1 - 1996/1/25

N2 - The title oligomers are obtainable by reacting a compd. contg. hydroxyaryl comprising >=3 hydroxyaryl groups 2-R2,4-R1,6-R3-C6H3OH (R1 = an arom., aliph. or cycloaliph. group contg. 1-50 C atoms, R2, R3 = H or an arom., aliph. or cycloaliph. group contg. 1-50 C atoms, or 2 of the R1, R2 or R3 groups together constitute a ring structure contg. 4-50 C atoms) with a polyphenylene oxide in the presence of a catalyst complex comprising a transition metal and amine. Hydroxy-terminal polyoxyphenylene [no.-av. mol. wt. (Mn) 8200] and tert-butylcalix(8)arene were mixed in CCl4 in the presence of CuCl2 and dimethylaminopyridine, bubbling through O:N mixt. for 40 h at room temp. to give an oligomer having Mn 11,590

AB - The title oligomers are obtainable by reacting a compd. contg. hydroxyaryl comprising >=3 hydroxyaryl groups 2-R2,4-R1,6-R3-C6H3OH (R1 = an arom., aliph. or cycloaliph. group contg. 1-50 C atoms, R2, R3 = H or an arom., aliph. or cycloaliph. group contg. 1-50 C atoms, or 2 of the R1, R2 or R3 groups together constitute a ring structure contg. 4-50 C atoms) with a polyphenylene oxide in the presence of a catalyst complex comprising a transition metal and amine. Hydroxy-terminal polyoxyphenylene [no.-av. mol. wt. (Mn) 8200] and tert-butylcalix(8)arene were mixed in CCl4 in the presence of CuCl2 and dimethylaminopyridine, bubbling through O:N mixt. for 40 h at room temp. to give an oligomer having Mn 11,590

UR - http://preview.espacenet.com/origdoc?DB=EPODOC&IDX=WO9601865&F=0&QPN=WO9601865

M3 - Patent publication

M1 - WO9601865 A1

ER -

Multihydroxy-functional oligophenylene oxide

Abstract

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