Morphology study of linear metallo-supramolecular polymer films

D. Wouters, A.A. Alexeev, H. Hofmeier, S. Schmatloch, U.S. Schubert

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At. force microscopy was used to study the thin film morphol. of metallo-supramol. polymers. Extended linear polymers were made through complexation of poly(ethylene glycol) pre-polymers with terpyridine end-groups by addn. of suitable iron and ruthenium salts. For polymers with poly(ethylene glycol) spacers, a double lamellar morphol. was obsd. This morphol. is lost upon melting at 50 Deg. For the polymer with a diethylene glycol spacer an amorphous film is formed that is stable up to 250 Deg
Original languageEnglish
Pages (from-to)345-346
JournalPolymer Preprints
Issue number1
Publication statusPublished - 2004


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