Mono- and Zerovalent Manganese Alkyl Complexes Supported by the α,α‘-Diiminato Pyridine Ligand:  Alkyl Stabilization at the Expense of Catalytic Performance

Damien Reardon; Ghazar Aharonian; Sandro Gambarotta; G.P.A. Yap

Mono- and Zerovalent Manganese Alkyl Complexes Supported by the α,α‘-Diiminato Pyridine Ligand: Alkyl Stabilization at the Expense of Catalytic Performance

Damien Reardon
, Ghazar Aharonian
, Sandro Gambarotta
, G.P.A. Yap

Research output: Contribution to journal › Article › Academic › peer-review

Abstract

The reaction of {[2,6-(i-Pr)2PhNC(Me)]2(C5H3N)}MnCl2 with MeLi or Me3SiCH2Li afforded reduction toward rare examples of non-cyclopentadienyl and non-carbonyl Mn(I) and Mn(0) alkyl derivatives.

Original language	English
Pages (from-to)	786-788
Journal	Organometallics
Volume	21
Issue number	5
Publication status	Published - 29 Jan 2002

Keywords

transition metals
Reaction products
alkyls
Metals
Ligands

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https://doi.org/10.1021/om0110078

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title = "Mono- and Zerovalent Manganese Alkyl Complexes Supported by the α,α{\textquoteleft}-Diiminato Pyridine Ligand: Alkyl Stabilization at the Expense of Catalytic Performance",

abstract = "The reaction of \{[2,6-(i-Pr)2PhNC(Me)]2(C5H3N)\}MnCl2 with MeLi or Me3SiCH2Li afforded reduction toward rare examples of non-cyclopentadienyl and non-carbonyl Mn(I) and Mn(0) alkyl derivatives.",

keywords = "transition metals, Reaction products, alkyls, Metals, Ligands",

author = "Damien Reardon and Ghazar Aharonian and Sandro Gambarotta and G.P.A. Yap",

year = "2002",

month = jan,

day = "29",

language = "English",

volume = "21",

pages = "786--788",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "5",

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TY - JOUR

T1 - Mono- and Zerovalent Manganese Alkyl Complexes Supported by the α,α‘-Diiminato Pyridine Ligand: Alkyl Stabilization at the Expense of Catalytic Performance

AU - Reardon, Damien

AU - Aharonian, Ghazar

AU - Gambarotta, Sandro

AU - Yap, G.P.A.

PY - 2002/1/29

Y1 - 2002/1/29

N2 - The reaction of {[2,6-(i-Pr)2PhNC(Me)]2(C5H3N)}MnCl2 with MeLi or Me3SiCH2Li afforded reduction toward rare examples of non-cyclopentadienyl and non-carbonyl Mn(I) and Mn(0) alkyl derivatives.

AB - The reaction of {[2,6-(i-Pr)2PhNC(Me)]2(C5H3N)}MnCl2 with MeLi or Me3SiCH2Li afforded reduction toward rare examples of non-cyclopentadienyl and non-carbonyl Mn(I) and Mn(0) alkyl derivatives.

KW - transition metals

KW - Reaction products

KW - alkyls

KW - Metals

KW - Ligands

M3 - Article

SN - 0276-7333

VL - 21

SP - 786

EP - 788

JO - Organometallics

JF - Organometallics

IS - 5

ER -

Mono- and Zerovalent Manganese Alkyl Complexes Supported by the α,α‘-Diiminato Pyridine Ligand: Alkyl Stabilization at the Expense of Catalytic Performance

Abstract

Keywords

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