Molecular weight control in emulsion polymerization by catalytic chain transfer : a reaction engineering approach

N.M.B. Smeets; U.S. Meda; J.P.A. Heuts; J.T.F. Keurentjes; A.M. Herk, van; J. Meuldijk

doi:10.1002/masy.200751346

Molecular weight control in emulsion polymerization by catalytic chain transfer : a reaction engineering approach

N.M.B. Smeets, U.S. Meda, J.P.A. Heuts, J.T.F. Keurentjes, A.M. Herk, van, J. Meuldijk

Chemical Engineering and Chemistry

Research output: Contribution to journal › Article › Academic › peer-review

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Abstract

For the application of catalytic chain transfer in (mini)emulsion polymerization, catalyst partitioning and deactivation are key parameters that govern the actual catalyst concentration at the locus of polymerization and consequently the final molecular weight distribution. A global model, based on the Mayo equation, catalyst partitioning and deactivation was developed. The influence of several reaction parameters on the instantaneous number average molecular weight was quantified.

Original language	English
Pages (from-to)	406-415
Journal	Macromolecular Symposia
Volume	259
Issue number	1
DOIs	https://doi.org/10.1002/masy.200751346
Publication status	Published - 2007

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title = "Molecular weight control in emulsion polymerization by catalytic chain transfer : a reaction engineering approach",

abstract = "For the application of catalytic chain transfer in (mini)emulsion polymerization, catalyst partitioning and deactivation are key parameters that govern the actual catalyst concentration at the locus of polymerization and consequently the final molecular weight distribution. A global model, based on the Mayo equation, catalyst partitioning and deactivation was developed. The influence of several reaction parameters on the instantaneous number average molecular weight was quantified.",

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AU - Smeets, N.M.B.

AU - Meda, U.S.

AU - Heuts, J.P.A.

AU - Keurentjes, J.T.F.

AU - Herk, van, A.M.

AU - Meuldijk, J.

PY - 2007

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AB - For the application of catalytic chain transfer in (mini)emulsion polymerization, catalyst partitioning and deactivation are key parameters that govern the actual catalyst concentration at the locus of polymerization and consequently the final molecular weight distribution. A global model, based on the Mayo equation, catalyst partitioning and deactivation was developed. The influence of several reaction parameters on the instantaneous number average molecular weight was quantified.

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DO - 10.1002/masy.200751346

M3 - Article

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SP - 406

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JO - Macromolecular Symposia

JF - Macromolecular Symposia

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Molecular weight control in emulsion polymerization by catalytic chain transfer : a reaction engineering approach

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