Modelling the active sites of heterogeneous titanium epoxidation catalysts using titanium silasesquioxanes: insight into specific factors that determine leaching in liquid-phase processes

H.C.L. Abbenhuis, S. Krijnen, R.A. Santen, van

Research output: Contribution to journalArticleAcademicpeer-review

138 Citations (Scopus)
112 Downloads (Pure)

Abstract

Active catalysts for the epoxidation of alkenes by tert-butyl hydroperoxide are provided by silasesquioxane titanium(IV) derivatives; a non-leaching catalyst, not prone to irreversible protic cleavage of its siloxy functions by the oxidizing agent, contains a terdentate silasesquioxane ligand
Original languageEnglish
Pages (from-to)331-332
Number of pages2
JournalChemical Communications
Volume1997
Issue number3
DOIs
Publication statusPublished - 1997

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