Mixed ionic-electronic conducting membranes (MIEC) for their application in membrane reactors: a review

Alba Arratibel Plazaola; Aitor Cruellas Labella; Yuliang Liu; Nerea Badiola Porras; David Alfredo Pacheco Tanaka; Martin Van Sint Annaland; Fausto Gallucci

doi:10.3390/pr7030128

Mixed ionic-electronic conducting membranes (MIEC) for their application in membrane reactors: a review

Alba Arratibel Plazaola, Aitor Cruellas Labella, Yuliang Liu, Nerea Badiola Porras, David Alfredo Pacheco Tanaka, Martin Van Sint Annaland, Fausto Gallucci (Corresponding author)

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Abstract

Mixed ionic-electronic conducting membranes have seen significant progress over the last 25 years as efficient ways to obtain oxygen separation from air and for their integration in chemical production systems where pure oxygen in small amounts is needed. Perovskite materials are the most employed materials for membrane preparation. However, they have poor phase stability and are prone to poisoning when subjected to CO ₂ and SO ₂ , which limits their industrial application. To solve this, the so-called dual-phase membranes are attracting greater attention. In this review, recent advances on self-supported and supported oxygen membranes and factors that affect the oxygen permeation and membrane stability are presented. Possible ways for further improvements that can be pursued to increase the oxygen permeation rate are also indicated. Lastly, an overview of the most relevant examples of membrane reactors in which oxygen membranes have been integrated are provided.

Original language	English
Article number	128
Number of pages	50
Journal	Processes
Volume	7
Issue number	3
DOIs	https://doi.org/10.3390/pr7030128
Publication status	Published - 1 Mar 2019

Keywords

Fluorite
Membrane
Membrane reactor
MIEC
Oxygen separation
Perovskite

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10.3390/pr7030128

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Cite this

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title = "Mixed ionic-electronic conducting membranes (MIEC) for their application in membrane reactors: a review",

abstract = " Mixed ionic-electronic conducting membranes have seen significant progress over the last 25 years as efficient ways to obtain oxygen separation from air and for their integration in chemical production systems where pure oxygen in small amounts is needed. Perovskite materials are the most employed materials for membrane preparation. However, they have poor phase stability and are prone to poisoning when subjected to CO 2 and SO 2 , which limits their industrial application. To solve this, the so-called dual-phase membranes are attracting greater attention. In this review, recent advances on self-supported and supported oxygen membranes and factors that affect the oxygen permeation and membrane stability are presented. Possible ways for further improvements that can be pursued to increase the oxygen permeation rate are also indicated. Lastly, an overview of the most relevant examples of membrane reactors in which oxygen membranes have been integrated are provided. ",

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author = "Plazaola, {Alba Arratibel} and Labella, {Aitor Cruellas} and Yuliang Liu and Porras, {Nerea Badiola} and Tanaka, {David Alfredo Pacheco} and Annaland, {Martin Van Sint} and Fausto Gallucci",

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T1 - Mixed ionic-electronic conducting membranes (MIEC) for their application in membrane reactors

T2 - a review

AU - Plazaola, Alba Arratibel

AU - Labella, Aitor Cruellas

AU - Liu, Yuliang

AU - Porras, Nerea Badiola

AU - Tanaka, David Alfredo Pacheco

AU - Annaland, Martin Van Sint

AU - Gallucci, Fausto

PY - 2019/3/1

Y1 - 2019/3/1

N2 - Mixed ionic-electronic conducting membranes have seen significant progress over the last 25 years as efficient ways to obtain oxygen separation from air and for their integration in chemical production systems where pure oxygen in small amounts is needed. Perovskite materials are the most employed materials for membrane preparation. However, they have poor phase stability and are prone to poisoning when subjected to CO 2 and SO 2 , which limits their industrial application. To solve this, the so-called dual-phase membranes are attracting greater attention. In this review, recent advances on self-supported and supported oxygen membranes and factors that affect the oxygen permeation and membrane stability are presented. Possible ways for further improvements that can be pursued to increase the oxygen permeation rate are also indicated. Lastly, an overview of the most relevant examples of membrane reactors in which oxygen membranes have been integrated are provided.

AB - Mixed ionic-electronic conducting membranes have seen significant progress over the last 25 years as efficient ways to obtain oxygen separation from air and for their integration in chemical production systems where pure oxygen in small amounts is needed. Perovskite materials are the most employed materials for membrane preparation. However, they have poor phase stability and are prone to poisoning when subjected to CO 2 and SO 2 , which limits their industrial application. To solve this, the so-called dual-phase membranes are attracting greater attention. In this review, recent advances on self-supported and supported oxygen membranes and factors that affect the oxygen permeation and membrane stability are presented. Possible ways for further improvements that can be pursued to increase the oxygen permeation rate are also indicated. Lastly, an overview of the most relevant examples of membrane reactors in which oxygen membranes have been integrated are provided.

KW - Fluorite

KW - Membrane

KW - Membrane reactor

KW - MIEC

KW - Oxygen separation

KW - Perovskite

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VL - 7

JO - Processes

JF - Processes

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M1 - 128

ER -

Mixed ionic-electronic conducting membranes (MIEC) for their application in membrane reactors: a review

Abstract

Keywords

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